scholarly journals Nucleation and growth of PrBa2Cu3O7−δ barrier layers on ramps in DyBa2Cu3O7−δ studied by atomic force microscopy

1996 ◽  
Vol 68 (9) ◽  
pp. 1276-1278 ◽  
Author(s):  
M. A. J. Verhoeven ◽  
R. Moerman ◽  
M. E. Bijlsma ◽  
A. J. H. M. Rijnders ◽  
D. H. A. Blank ◽  
...  
1998 ◽  
Vol 125 (1) ◽  
pp. 58-64 ◽  
Author(s):  
R. Castro-Rodriguez ◽  
A.I. Oliva ◽  
M. Aguilar ◽  
P. Bartolo-Perez ◽  
E. Vasco ◽  
...  

1994 ◽  
Vol 76 (7) ◽  
pp. 4099-4106 ◽  
Author(s):  
M. A. George ◽  
A. Burger ◽  
W. E. Collins ◽  
J. L. Davidson ◽  
A. V. Barnes ◽  
...  

2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Sergey Yu. Luchkin ◽  
Svetlana A. Lipovskikh ◽  
Natalia S. Katorova ◽  
Aleksandra A. Savina ◽  
Artem M. Abakumov ◽  
...  

Abstract Li-ion battery performance and life cycle strongly depend on a passivation layer called solid-electrolyte interphase (SEI). Its structure and composition are studied in great details, while its formation process remains elusive due to difficulty of in situ measurements of battery electrodes. Here we provide a facile methodology for in situ atomic force microscopy (AFM) measurements of SEI formation on cross-sectioned composite battery electrodes allowing for direct observations of SEI formation on various types of carbonaceous negative electrode materials for Li-ion batteries. Using this approach, we observed SEI nucleation and growth on highly oriented pyrolytic graphite (HOPG), MesoCarbon MicroBeads (MCMB) graphite, and non-graphitizable amorphous carbon (hard carbon). Besides the details of the formation mechanism, the electrical and mechanical properties of the SEI layers were assessed. The comparative observations revealed that the electrode potentials for SEI formation differ depending on the nature of the electrode material, whereas the adhesion of SEI to the electrode surface clearly correlates with the surface roughness of the electrode. Finally, the same approach applied to a positive LiNi1/3Mn1/3Co1/3O2 electrode did not reveal any signature of cathodic SEI thus demonstrating fundamental differences in the stabilization mechanisms of the negative and positive electrodes in Li-ion batteries.


2009 ◽  
Vol 16 (01) ◽  
pp. 19-22
Author(s):  
Y. L. GENG ◽  
Z. H. SUN

Growth mechanisms and defects formation of the manganese mercury thiocyanate (MMTC) crystal have been investigated by atomic force microscopy (AFM). Both screw dislocation controlled growth and 2D nucleation growth occur on the {110} faces. Stacking faults are observed among dislocation hillocks and the formation of them probably results from the different crystallization orientations of different spirals. Hollow channels are found around the nucleation islands and the formation of them is due to the instability of the interface generated by the rapid nucleation and growth speeds.


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