Toroidal crystal spectrometer for time-resolved x-ray absorption diagnostic in dense plasmas

1999 ◽  
Vol 70 (8) ◽  
pp. 3314-3318 ◽  
Author(s):  
Francesca Pisani ◽  
Michel Koenig ◽  
Dimitri Batani ◽  
Tom Hall ◽  
Denis Desenne ◽  
...  
2004 ◽  
Vol 75 (1) ◽  
pp. 24-30 ◽  
Author(s):  
Melanie Saes ◽  
Frank van Mourik ◽  
Wojciech Gawelda ◽  
Maik Kaiser ◽  
Majed Chergui ◽  
...  

2022 ◽  
Vol 29 (1) ◽  
Author(s):  
Yujin Kim ◽  
Daewoong Nam ◽  
Rory Ma ◽  
Sangsoo Kim ◽  
Myung-jin Kim ◽  
...  

Understanding the ultrafast dynamics of molecules is of fundamental importance. Time-resolved X-ray absorption spectroscopy (TR-XAS) is a powerful spectroscopic technique for unveiling the time-dependent structural and electronic information of molecules that has been widely applied in various fields. Herein, the design and technical achievement of a newly developed experimental apparatus for TR-XAS measurements in the tender X-ray range with X-ray free-electron lasers (XFELs) at the Pohang Accelerator Laboratory XFEL (PAL-XFEL) are described. Femtosecond TR-XAS measurements were conducted at the Ru L 3-edge of well known photosensitizer tris(bipyridine)ruthenium(II) chloride ([Ru(bpy)3]2+) in water. The results indicate ultrafast photoinduced electron transfer from the Ru center to the ligand, which demonstrates that the newly designed setup is applicable for monitoring ultrafast reactions in the femtosecond domain.


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