Coupling of gas chromatography and molecular beam/mass spectrometry analytical techniques: Application to flame structure study

1999 ◽  
Vol 70 (6) ◽  
pp. 2828-2835 ◽  
Author(s):  
A. Turbiez ◽  
P. Devynck ◽  
P. Desgroux ◽  
J. F. Pauwels
Keyword(s):  
Mass Spectrometry ◽  
Gas Chromatography ◽  
Molecular Beam ◽  
Flame Structure ◽  
Analytical Techniques ◽  
Structure Study ◽  
Molecular Beam Mass Spectrometry

Flame structure study of a lean H2/N2O/Ar Flame employing molecular beam mass spectrometry and modeling

1994 ◽  
Vol 99 (2) ◽  
pp. 323-330 ◽  
Author(s):  
David C. Dayton ◽  
Cynthia M. Faust ◽  
William R. Anderson ◽  
Rosario C. Sausa
Keyword(s):  
Mass Spectrometry ◽  
Molecular Beam ◽  
Flame Structure ◽  
Structure Study ◽  
Molecular Beam Mass Spectrometry

Ethanol flame structure investigated by molecular beam mass spectrometry

2007 ◽  
Vol 150 (3) ◽  
pp. 220-231 ◽  
Author(s):  
T KASPER ◽  
P OSWALD ◽  
M KAMPHUS ◽  
K KOHSEHOINGHAUS
Keyword(s):  
Mass Spectrometry ◽  
Molecular Beam ◽  
Flame Structure ◽  
Molecular Beam Mass Spectrometry ◽  
Ethanol Flame

Study of the CL-20 flame structure using probing molecular beam mass spectrometry

2009 ◽  
Vol 45 (3) ◽  
pp. 286-292 ◽  
Author(s):  
A. A. Paletsky ◽  
A. G. Tereshchenko ◽  
E. N. Volkov ◽  
O. P. Korobeinichev ◽  
G. V. Sakovich ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Molecular Beam ◽  
Flame Structure ◽  
Molecular Beam Mass Spectrometry

Investigation of Methyl Pentanoate Flame Structure by Molecular-Beam Mass Spectrometry and Modeling

2014 ◽  
Vol 9 (3) ◽  
pp. 49-62
Author(s):  
Iliya Gerasimov ◽  
Denis Knyazkov ◽  
Andrey Shmakov ◽  
Oleg Korobeinichev ◽  
Nils Hansen ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Carbon Monoxide ◽  
Molecular Beam ◽  
Flame Structure ◽  
Chemical Kinetic ◽  
Concentration Profiles ◽  
Molecular Beam Mass Spectrometry ◽  
Kinetic Mechanisms ◽  
Modeling Data ◽  
Detailed Chemical

The structure of four stoichiometric and fuel-rich premixed flames of methyl pentanoate stabilized at low (20 torr) and atmospheric pressures has been studied by molecular-beam mass spectrometry. The data obtained have been compared with results of numerical simulations, performed with implication of two detailed chemical kinetic mechanisms, one of which has been developed by the authors of this work. While both mechanisms have predicted concentration profiles for most of the species quite well, some discrepancies between experimental and modeling data have been observed for carbon monoxide and some intermediate products. Considerable differences in several profiles simulated with different mechanisms have been noted. Analysis of reaction paths in investigated flames has shown most of these differences to be caused by different reactions and kinetics used for isomerization of primary radicals of methyl pentanoate oxidation in these mechanisms

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