Energy dispersive x‐ray diffraction from high pressure polycrystalline specimens using synchrotron radiation

1981 ◽  
Vol 52 (11) ◽  
pp. 1616-1624 ◽  
Author(s):  
Millard A. Baublitz ◽  
Volker Arnold ◽  
Arthur L. Ruoff
Keyword(s):  
High Pressure ◽  
Synchrotron Radiation ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray

A full-pattern fitting algorithm for energy-dispersive X-ray diffraction

2003 ◽  
Vol 36 (5) ◽  
pp. 1123-1127 ◽  
Author(s):  
Yu-Hui Dong ◽  
Jing Liu ◽  
Yan-Chun Li ◽  
Xiao-Dong Li
Keyword(s):  
High Pressure ◽  
Energy Dispersive ◽  
X Ray Diffraction ◽  
X Ray ◽  
Cell Parameters ◽  
Fitting Algorithm ◽  
Diffraction Angle ◽  
Data Points ◽  
Diffraction Peaks ◽  
Very High

A full-pattern fitting algorithm for energy-dispersive X-ray diffraction is proposed, especially for high-pressure X-ray diffraction studies. The algorithm takes into account the errors in measuring the energy and the diffraction angle. A lognormal function is introduced to represent the background. All the peaks that are detectable in the diffraction spectra, including fluorescence and diffraction peaks, are considered together. Because all the data points in the spectra are used, the accuracy of the cell parameters obtained by this method is very high. This is very helpful in the analysis of the equation of state and the identification of new phases under high pressure.

High-pressure x-ray diffraction station at the beijing synchrotron radiation facility

1992 ◽  
Vol 8 (5-6) ◽  
pp. 711-713
Author(s):  
Yuechao Zhao ◽  
Rongzheng Che ◽  
Esheng Tang ◽  
Dingchang Xian
Keyword(s):  
High Pressure ◽  
Synchrotron Radiation ◽  
X Ray Diffraction ◽  
X Ray ◽  
Beijing Synchrotron Radiation Facility

scholarly journals In-situhigh-pressure powder X-ray diffraction study of α-zirconium phosphate

2014 ◽  
Vol 70 (3) ◽  
pp. 510-516
Author(s):  
Jennifer E. Readman ◽  
Alistair Lennie ◽  
Joseph A. Hriljac
Keyword(s):  
High Pressure ◽  
Synchrotron Radiation ◽  
Zirconium Phosphate ◽  
Water Molecules ◽  
X Ray Diffraction ◽  
X Ray ◽  
Additional Water ◽  
Diffraction Patterns ◽  
Layered Phosphate

The high-pressure structural chemistry of α-zirconium phosphate, α-Zr(HPO4)2·H2O, was studied usingin-situhigh-pressure diffraction and synchrotron radiation. The layered phosphate was studied under both hydrostatic and non-hydrostatic conditions and Rietveld refinement carried out on the resulting diffraction patterns. It was found that under hydrostatic conditions no uptake of additional water molecules from the pressure-transmitting medium occurred, contrary to what had previously been observed with some zeolite materials and a layered titanium phosphate. Under hydrostatic conditions the sample remained crystalline up to 10 GPa, but under non-hydrostatic conditions the sample amorphized between 7.3 and 9.5 GPa. The calculated bulk modulus,K0= 15.2 GPa, showed the material to be very compressible with the weak linkages in the structure of the type Zr—O—P.

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