Improvements on the measurements of dielectric constant and dissipation factor in a wide frequency range

1977 ◽  
Vol 48 (12) ◽  
pp. 1570-1575 ◽  
Author(s):  
A. Kakimoto ◽  
I. Ogawa ◽  
T. Matsushita
Author(s):  
A. V. Repin

The results of measuring the complex dielectric constant of clays saturated with an oil-water emulsion in various ratios in a wide frequency range are presented. The measurements were used out at positive and negative temperatures. It was revealed that several relaxation processes are observed in the spectra. The processes parameters significantly depend on the temperature and the ratio of water and hydrocarbon to the saturating mixture. A model is proposed that makes it possible to take into account relaxation processes and their dependence on temperature.


2016 ◽  
Vol 49 (4) ◽  
pp. 281-297 ◽  
Author(s):  
Lina Dong ◽  
Wenying Zhou ◽  
Xuezhen Sui ◽  
Zijun Wang ◽  
Peng Wu ◽  
...  

Epoxy (Ep) resin modified with carboxyl-terminated polybutadiene (CTPB) liquid rubber was investigated in this study. Fourier transform infrared verified the chemical reactions between oxirane ring of Ep and carboxyl groups of CTPB using benzyldimethylamine as a catalyst. The decrease of the thermal stability could be due to the lower thermal stability of CTPB compared with that of pure Ep. The mechanical results showed that CTPB-modified Ep was superior to that of the pure Ep, and the best overall mechanical properties were normally achieved with 20 phr of CTPB content. The impact strength of the system containing 20 phr CTPB increased by 193% due to the two-phase nature of the system. The dielectric constant and dissipation factor of the modified Ep obviously declined with the CTPB content compared with pure Ep, for instance, the dissipation factor remained less than 0.02 in wide frequency range.


2015 ◽  
Vol 1107 ◽  
pp. 38-44
Author(s):  
Wong Yick Jeng ◽  
Hassan Jumiah ◽  
Mansor Hashim

The CaTiO3samples were prepared by high-energy ball milling process followed by sintering process from 1040 to 1200°C. X-ray diffraction (XRD), microstructural analysis, and dielectric properties over a wide range of frequency varying from 0.01 Hz to 1 GHz at room temperature were investigated. The formation of a single phase CaTiO3with orthorhombic structure was achieved at 1120°C and above. From a morphological point of view, sintering temperature promoted grain growth. Dielectric properties in the frequency range 0.01 Hz - 1 MHz revealed a relaxation-type process. Interfacial phenomena were the possible physical mechanisms that gave rise to these relaxation-type plots. Extending the frequencies above ~1 MHz yielded a frequency-independent characteristic of dielectric constant (ε'). These turned out to the relatively small dielectric loss (tan δ) values. The origin of the dielectric responses in the frequency range 1 MHz - 1 GHz was attributed to the domination of dipolar polarization. The grain size effect in sintered CaTiO3samples was prominent, notably in dielectric responses above ~1 MHz. Increase in sintering temperature remarkably led to an enhancement in dielectric constant values and reduction in dielectric loss values. Therefore, a significant correlation existed between microstructural features and dielectric properties.


2013 ◽  
Vol 750-752 ◽  
pp. 492-496
Author(s):  
Peng Fei Wei

The behavior of dielectric and microwave properties against sintering temperature was been carried out on CaO-B2O3-SiO2glass-ceramics with Na2O addition by XRD and SEM. The results show that 0.5 wt.% Na2O addition is advantageous to improve the dielectric and microwave properties due to increasing the major crystalline CaSiO3. With further increasing Na2O content, α-SiO2is the predominant crystalline phase instead of CaSiO3. The CBS glass-ceramics with 0.5 wt.% Na2O sintered at 875°C has a bulk density of 2.51g·cm-3, and which possesses good dielectric properties:εr=6.2,tanδ=1.9×10-3(10 MHz) and low dielectric constant below 2×10-3over a wide frequency range. The proposed dielectrics can find applications in microwave devices, which require low dielectric loss and low dielectric constant.


2011 ◽  
Vol 279 ◽  
pp. 3-9
Author(s):  
Yu Сhao Li ◽  
Xiang Сai Ge ◽  
Sie Chin Tjong

Binary poly(vinylidene fluoride)/silicon carbide (PVDF/SiC) composites and its graphite nanosheets (GN) doped ternary hybrids were fabricated using simple solution mixing and hot compression molding process. The dielectric behavior of such hybrids was studied over a wide frequency range. Additions of graphite nanosheets with their concentrations close to the percolation threshold were found to be very effective to enhance the dielectric permittivity of PVDF/SiC system. The dielectric constant for PVDF/SiC/GN 80/20/2 system was ~ 200, being twenty times higher than that of neat PVDF. Furthermore, the dielectric behavior of such hybrid displayed strong frequency dependence.


Author(s):  
Anatolii G. Belous ◽  
◽  
Oleg I. V'yunov ◽  
Oleg Z. Yanchevskii ◽  
Leonid L. Kovalenko ◽  
...  

Materials with a high dielectric constant (e > 1000) based on complex oxides of spontaneously polarized systems, lithium-conducting systems, and oxides of transition metals were studied. It was shown in dielectric ceramics Ba(Ti,Sn)O3 the absence of significant dispersion of dielectric parameters (e and tg δ) in a wide frequency range from 1 to 105 Hz. The introduction of MnO2 and Al2O3-SiO2-TiO2 improves dielectric parameters and reduces sintering temperature. Obtained ceramic materials are characterized by high dielectric constant values e ~ 13000–16000 and low dielectric losses tg d ~ 0.05–0.06 (at 1 MHz). Synthesized solid solutions of La0.5Li0.5-xNaxTiO3 system, where x = 0 and 0.1, have high values e¢ > 104 at low frequencies (f ≤ 10 Hz). Dielectric properties of these materials are determined by the lithium ions mobility that increases with the rise of sodium content by increasing bottleneck size and decreases by the number of lithium vacancies reduction. The disadvantage of such materials is the decrease in dielectric constant with frequency increase. It was found that the ceramic СaСu3Тi4–xAlxО12-y-0.5xFy with x/y = 0.04/0.04 after sintering for 10 h is characterized by dielectric parameters: e¢ » 71000 (1 kHz) and tg d » 0.047. Introduction of aluminum (x/y = 0.04/0) or fluorine (0/0.08) in CCTO reduces dielectric losses (tg d » 0.044). The advantages of this type of material are a wide frequency range of high dielectric constant and relatively low dielectric loss. Synthesized materials can be used for the development of ceramic capacitors with high characteristics.


Author(s):  
A. V. Repin ◽  
O. V. Rodionova

The article presents the results of measurements of the complex dielectric constant of clays saturated with NaCl solution of various concentrations in a wide frequency range. The measurements were carried out at positive temperatures. It was revealed that several relaxation processes are observed in the spectra. A model is proposed that makes it possible to take into account the relaxation processes and their dependence on the concentration of the salt solution. The concentration practically does not affect the parameters of the processes, in contrast to the temperature.


2016 ◽  
Vol 06 (03) ◽  
pp. 1650021
Author(s):  
Vaibhav Shrivastava

In this paper, effects of lattice strain on dielectric properties of Sr[Formula: see text]CaxBi2Nb2O9 ([Formula: see text]–0.5 in steps of 0.1) ceramics are reported. High frequency dipolar polarization is observed to increase for 10% calcium addition and suppresses thereafter on higher calcium concentrations. The dielectric loss values for all doped samples were lower compared to undoped one at frequencies beyond 1[Formula: see text]kHz. The sample with [Formula: see text] shows room temperature dielectric constant in the range (130[Formula: see text][Formula: see text][Formula: see text]12) over a wide frequency range from 50[Formula: see text]Hz to 1[Formula: see text]MHz also minimum dielectric loss among all other sample for the same frequency range. Remarkable increase in Curie temperature ([Formula: see text]) by 50[Formula: see text]C is recorded in the present work by increasing 10% calcium content in SBN compostion. All higher doped samples indicate increase in [Formula: see text] by further higher amount. In addition, dc conductivity of all samples is measured for all samples and increase in calcium content is observed to generate more insulating compositions compared to undoped SBN with higher intrinsic activation energies.


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