Representative reflectance anisotropy spectra from Al(x)Ga(1−x)As layers (x=0 to 1.0) grown on GaAs(001) by molecular beam epitaxy

1995 ◽  
Vol 66 (15) ◽  
pp. 1930-1932 ◽  
Author(s):  
K. C. Rose ◽  
S. J. Morris ◽  
D. I. Westwood ◽  
D. A. Woolf ◽  
R. H. Williams ◽  
...  
1995 ◽  
Vol 337 (1-2) ◽  
pp. 103-108 ◽  
Author(s):  
J. Rumberg ◽  
J.-T. Zettler ◽  
K. Stahrenberg ◽  
K. Ploska ◽  
W. Richter ◽  
...  

1993 ◽  
Vol 63 (4) ◽  
pp. 503-505 ◽  
Author(s):  
S. R. Armstrong ◽  
M. E. Pemble ◽  
A. G. Taylor ◽  
P. N. Fawcette ◽  
J. H. Neave ◽  
...  

1996 ◽  
Vol 164 (1-4) ◽  
pp. 40-46 ◽  
Author(s):  
J. Zhang ◽  
A.K. Lees ◽  
A.G. Taylor ◽  
D. Raisbeck ◽  
N. Shukla ◽  
...  

1998 ◽  
Vol 05 (03n04) ◽  
pp. 761-767 ◽  
Author(s):  
B. A. Joyce ◽  
J. Zhang ◽  
A. G. Taylor ◽  
A. K. Lees

Molecular beam epitaxy (MBE) provides an ideal experimental vehicle for the in situ study of thin film growth dynamics. By using a combination of reflection high energy electron diffraction (RHEED) and reflectance anisotropy (difference) spectroscopy [RA(D)S], it is possible to separate morphological (long range order) and local electronic structure effects, which we demonstrate with the growth of silicon films from disilane ( Si 2 H 6) on Si(001) (2 × 1)+(1 × 2) reconstructed surfaces. The rate-limiting step in Si growth from both monosilane ( SiH 4) and disilane is the desorption of molecular hydrogen and we have found using RAS that, over a significant range of temperature and coverage, hydrogen desorption follows zeroth order kinetics as the result of a step-mediated process. Finally, we show how this influences the growth rate on substrates of differing degrees of vicinality.


1993 ◽  
Vol 334 ◽  
Author(s):  
K. Ploska ◽  
W. Richter ◽  
F. Reinhardt ◽  
J. JÖnsson ◽  
J. Rumberg ◽  
...  

AbstractReflectance anisotropy spectroscopy (RAS) is presented as real time analytical tool for metalorganic vapourphase epitaxy (MOVPE) of III-V-semiconductors. This optical method derives its surface sensitivity from the anisotropy of surface structures. It is shown that it is possible to monitor with RAS the oxide desorption from the substrate and that the substrate surface conditions thereafter, still in the pregrowth stage, can be correlated with certain reconstructions of the (001)-surfaces of InP and GaAs. The latter is possible through simultaneous RAS and RHEED measurements during MBE (molecular beam epitaxy) or MOMBE (metalorganic molecular beam epitaxy). Characteristic spectral features are also observed for other binary or ternary III-V-semiconductors. Time resolved measurements during growth give monolayer resolution for the growth rate in the case of GaAs. In the study of heterointerface growth exchange reactions between As and P together with their corresponding reaction time constants can be monitored and conclusions for the epitaxial growth procedure can be drawn.


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