Piezoelectricity and electrostriction of dye‐doped polymer electrets

1994 ◽  
Vol 64 (11) ◽  
pp. 1347-1349 ◽  
Author(s):  
H.‐J. Winkelhahn ◽  
H. H. Winter ◽  
D. Neher
Keyword(s):  
Piezoelectricity And Electrostriction ◽  
Doped Polymer ◽  
Polymer Electrets

Tuning of Electronic Properties in Conducting Polymers

2001 ◽  
Vol 66 (8) ◽  
pp. 1208-1218 ◽  
Author(s):  
Guofeng Li ◽  
Mira Josowicz ◽  
Jiří Janata
Keyword(s):  
Hydrogen Bonding ◽  
Binding Site ◽  
Binding Sites ◽  
Polymer Chains ◽  
Electronic Transitions ◽  
Weakly Bound ◽  
Ordered Structures ◽  
Doped Polymer ◽  
Positively Charged ◽  
Repeated Cycling

Structural and electronic transitions in poly(thiophenyleneiminophenylene), usually referred to as poly(phenylenesulfidephenyleneamine) (PPSA) upon electrochemical doping with LiClO4 have been investigated. The unusual electrochemical behavior of PPSA indicates that the dopant anions are bound in two energetically different sites. In the so-called "binding site", the ClO4- anion is Coulombically attracted to the positively charged S or N sites on one chain and simultaneously hydrogen-bonded with the N-H group on a neighboring polymer chain. This strong interaction causes a re-organization of the polymer chains, resulting in the formation of a networked structure linked together by these ClO4- Coulombic/hydrogen bonding "bridges". However, in the "non-binding site", the ClO4- anion is very weakly bound, involves only the electrostatic interaction and can be reversibly exchanged when the doped polymer is reduced. In the repeated cycling, the continuous and alternating influx and expulsion of ClO4- ions serves as a self-organizing process for such networked structures, giving rise to a diminishing number of available "non-binding" sites. The occurrence of these ordered structures has a major impact on the electrochemical activity and the morphology of the doped polymer. Also due to stabilization of the dopant ions, the doped polymer can be kept in a stable and desirable oxidation state, thus both work function and conductivity of the polymer can be electrochemically controlled.

Charge Trapping in Polymer Electrets with Highly Dilute Blended Arylamine Donors

2021 ◽  
Author(s):  
Evan C. Plunkett ◽  
Qingyang Zhang ◽  
Howard E. Katz ◽  
Daniel H. Reich
Keyword(s):  
Charge Trapping ◽  
Polymer Electrets

scholarly journals Polymer electrets and their applications

2020 ◽  
pp. 50406
Author(s):  
Xin Li ◽  
Yurui Wang ◽  
Minxuan Xu ◽  
Yueqin Shi ◽  
Hemiao Wang ◽  
...  
Keyword(s):  
Polymer Electrets

Gamma-ray attenuation behaviors of hematite doped polymer composites

2020 ◽  
Vol 129 ◽  
pp. 103504 ◽  
Author(s):  
Mehmet Fatih Turhan ◽  
Ferdi Akman ◽  
Hasan Polat ◽  
Mustafa Recep Kaçal ◽  
İskender Demirkol
Keyword(s):  
Polymer Composites ◽  
Gamma Ray ◽  
Gamma Ray Attenuation ◽  
Doped Polymer

Doped polymer films with high nonlinear refractive indices

1996 ◽  
Vol 32 (2) ◽  
pp. 129 ◽  
Author(s):  
Z.X. Zhang ◽  
W. Qiu ◽  
E.Y.B. Pun ◽  
P.S. Chung ◽  
Y.Q. Shen
Keyword(s):  
Polymer Films ◽  
Refractive Indices ◽  
Doped Polymer

Synthesis and properties of a sterically encumbered poly(thienylene vinylene): poly[E-1,2-(4,4prime-dihexyl-2,2prime-dithienyl)ethylene]

1998 ◽  
Vol 76 (11) ◽  
pp. 1524-1529
Author(s):  
Jimmy Lowe ◽  
Carl Bartels ◽  
Steven Holdcroft
Keyword(s):  
Ftir Spectroscopy ◽  
Electrically Conducting ◽  
H Nmr ◽  
Visible Photoluminescence ◽  
Micron Size ◽  
Visible Irradiation ◽  
Uv Visible ◽  
The Stability ◽  
Doped Polymer ◽  
Polythiophene Derivative

Electrically conducting poly[E-1,2-(4,4prime-dihexyl-2,2prime-dithienyl)ethylene] was synthesized and structurally characterized by UV-visible, 1H NMR, and FTIR spectroscopy. The head-to-head arrangement of the alkylthiophene dyads directly affects the UV-visible, photoluminescence, and electroluminescence maxima of the polymer. The conductivity of the doped polymer was measured to be ~2 S cm-1 and the stability of the oxidized polymer possessing various dopants was compared. UV-visible irradiation of PDHDTE rendered the films insoluble and photolithography was used to produce micron-size images. FTIR was used to monitor the photoproducts during photolysis of PDHDTE. Mechanisms of photooxidation were proposed, based on the photoproducts observed.Key words: polythiophene derivative, head-to-head dyad, photolithography, photooxidation, electroluminescence.

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