Charge transfer from poly( p‐phenylene vinylene) into molecularly doped polymer

1993 ◽  
Vol 62 (24) ◽  
pp. 3167-3169 ◽  
Author(s):  
H. Antoniadis ◽  
B. R. Hsieh ◽  
M. A. Abkowitz ◽  
M. Stolka
Keyword(s):  
Charge Transfer ◽  
Phenylene Vinylene ◽  
Doped Polymer

Charge Transfer in Supramolecular Coaggregates of Oligo(p-Phenylene Vinylene) and Perylene Bisimide in Water

ChemPhysChem ◽  
2005 ◽  
Vol 6 (10) ◽  
pp. 2029-2031 ◽  
Author(s):  
Edwin H. A. Beckers ◽  
Pascal Jonkheijm ◽  
Albertus P. H. J. Schenning ◽  
Stefan C. J. Meskers ◽  
René A. J. Janssen
Keyword(s):  
Charge Transfer ◽  
Phenylene Vinylene ◽  
Perylene Bisimide

Variational studies on charge transfer in a molecularly doped polymer

1997 ◽  
Author(s):  
Zhi G. Yu ◽  
Avadh B. Saxena ◽  
Alan R. Bishop
Keyword(s):  
Charge Transfer ◽  
Doped Polymer

scholarly journals The Effect of Plasticizers on the Polypyrrole-Poly(vinyl alcohol)-Based Conducting Polymer Electrolyte and Its Application in Semi-Transparent Dye-Sensitized Solar Cells

Membranes ◽  
2021 ◽  
Vol 11 (10) ◽  
pp. 791
Author(s):  
KM Manikandan ◽  
Arunagiri Yelilarasi ◽  
SS Saravanakumar ◽  
Raed H. Althomali ◽  
Anish Khan ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Polymer Electrolyte ◽  
Vinyl Alcohol ◽  
Ethylene Carbonate ◽  
Dye Sensitized Solar Cells ◽  
Charge Transfer Resistance ◽  
Poly Vinyl Alcohol ◽  
Average Roughness ◽  
Transfer Resistance ◽  
Doped Polymer

In this work, the quasi-solid-state polymer electrolyte containing poly(vinyl alcohol)-polypyrrole as a polymer host, potassium iodide (KI), iodine (I2), and different plasticizers (EC, PC, GBL, and DBP) was successfully prepared via the solution casting technique. Fourier transform infrared spectroscopy (FTIR) was used to analyze the interaction between the polymer and the plasticizer. X-ray diffraction confirmed the reduction of crystallinity in the polymer electrolyte by plasticizer doping. The ethylene carbonate-based polymer electrolyte showed maximum electrical conductivity of 0.496 S cm−1. The lowest activation energy of 0.863 kJ mol−1 was obtained for the EC-doped polymer electrolyte. The lowest charge transfer resistance Rct1 was due to a faster charge transfer at the counter electrode/electrolyte interface. The polymer electrolyte containing the EC plasticizer exhibited an average roughness of 23.918 nm. A photo-conversion efficiency of 4.19% was recorded in the DSSC with the EC-doped polymer electrolyte under the illumination of 100 mWcm−2.

Photoinduced charge transfer in poly(p-phenylene vinylene) derivatives and carbon nanotube/C60 composites

2003 ◽  
Vol 338 (1-4) ◽  
pp. 366-369 ◽  
Author(s):  
C. Yang ◽  
M. Wohlgenannt ◽  
Z.V. Vardeny ◽  
W.J. Blau ◽  
A.B. Dalton ◽  
...  
Keyword(s):  
Charge Transfer ◽  
Carbon Nanotube ◽  
Phenylene Vinylene ◽  
Photoinduced Charge Transfer ◽  
Photoinduced Charge

Space-Charge-Limited Charge Injection From Ito/Ppv Into A Trap-Free Molecularly Doped Polymer

1993 ◽  
Vol 328 ◽  
Author(s):  
H. Antoniadis ◽  
M. Abkowitz ◽  
B. R. Hsieh ◽  
S. A. Jenekhe ◽  
M. Stolka
Keyword(s):  
Space Charge ◽  
Tin Oxide ◽  
Indium Tin Oxide ◽  
Dark Current ◽  
Phenylene Vinylene ◽  
Electroluminescent Devices ◽  
Hole Transporting ◽  
Novel Method ◽  
Doped Polymer ◽  
Space Charge Limited

ABSTRACTWe describe bilayer structures comprised of a poly (p-phenylene vinylene) (PPV) layer and a trap-free diaryldiamine (TPD) doped in polycarbonate (PC) layer, sandwiched between indium-tin-oxide (ITO) and aluminum (Al) contacts. Two critical phenomena in the operation of polymer based electroluminescent devices, interface injection and carrier range, are investigated. It is established that the ITO/PPV contact is capable of sustaining dark current under trap-free space-charge-limited (TFSCL) conditions into a hole transporting TPD:PC layer. TFSCL currents are not observed in devices without the PPV layer. Upon increasing the thickness of the PPV layer a deviation from the TFSCL regime is observed which is attributed to trapping of the injected holes within PPV. These observations suggest a novel method for estimating the trapping Mobility-lifetime product μτ for holes in PPV. By this means we estimate μτ ∼ 10−9 cm2/V.

Ratiometric pressure sensors based on cyano-substituted oligo(p-phenylene vinylene) derivatives in the hybridized local and charge-transfer excited state

2016 ◽  
Vol 4 (42) ◽  
pp. 9954-9960 ◽  
Author(s):  
Yujian Zhang ◽  
Moge Qile ◽  
Jingwei Sun ◽  
Minhong Xu ◽  
Kai Wang ◽  
...  
Keyword(s):  
Excited State ◽  
Charge Transfer ◽  
Pressure Sensors ◽  
Phenylene Vinylene ◽  
Emission Efficiency ◽  
High Emission

D–A type dye exhibits high emission efficiency and ratiometric piezochromism behavior due to HLCT characteristics.

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