Naturally Occurring α-Amino Acid Catalyzed Coupling of Carbon Dioxide with Epoxides to Afford Cyclic Carbonates

Synlett ◽  
2007 ◽  
Vol 2007 (2) ◽  
pp. 0255-0258 ◽  
Author(s):  
Huanfeng Jiang ◽  
Chaorong Qi ◽  
Zhaoyang Wang ◽  
Bo Zou ◽  
Shaorong Yang
Keyword(s):  
Carbon Dioxide ◽  
Amino Acid ◽  
Cyclic Carbonates ◽  
Naturally Occurring ◽  
Acid Catalyzed

Naturally Occurring α-Amino Acid Catalyzed Coupling of Carbon Dioxide with Epoxides to Afford Cyclic Carbonates.

ChemInform ◽  
2007 ◽  
Vol 38 (23) ◽  
Author(s):  
Chaorong Qi ◽  
Huanfeng Jiang ◽  
Zhaoyang Wang ◽  
Bo Zou ◽  
Shaorong Yang
Keyword(s):  
Carbon Dioxide ◽  
Amino Acid ◽  
Cyclic Carbonates ◽  
Naturally Occurring ◽  
Acid Catalyzed

Synthesis of Cyclic Carbonate From Carbon Dioxide and Epoxide Using Amino Acid Ionic Liquid Under 1atm Pressure

2012 ◽  
Vol 65 (4) ◽  
pp. 381 ◽  
Author(s):  
Qing Gong ◽  
Huadong Luo ◽  
Jin Cao ◽  
Yuhan Shang ◽  
Haibo Zhang ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Ionic Liquid ◽  
Amino Acid ◽  
Atmospheric Pressure ◽  
Cyclic Carbonate ◽  
Cyclic Carbonates ◽  
Metal Component ◽  
Co Catalyst ◽  
Effective Synthesis ◽  
Amino Acid Ionic Liquid

Herein, we report an effective synthesis of cyclic carbonates by cycloaddition of carbon dioxide to epoxide using a modified amino acid ionic liquid as catalyst under 1 atm pressure. With triethylamine as co-catalyst, the catalytic activity of the l-proline based ionic liquid was greatly enhanced, and up to 97 % isolated yield of cyclic carbonate was achieved at 90°C under atmospheric pressure without organic solvent and metal component.

Naturally Occurring Organic Acid-catalyzed Facile Diastereoselective Synthesis of Biologically Active (E)-3-(arylimino)indolin-2-one Derivatives in Water at Room Temperature

2019 ◽  
Vol 23 (16) ◽  
pp. 1778-1788 ◽  
Author(s):  
Gurpreet Kaur ◽  
Arvind Singh ◽  
Kiran Bala ◽  
Mamta Devi ◽  
Anjana Kumari ◽  
...  
Keyword(s):  
Room Temperature ◽  
Biologically Active ◽  
Environmentally Benign ◽  
Diastereoselective Synthesis ◽  
Substituted Anilines ◽  
Reaction Conditions ◽  
Naturally Occurring ◽  
Acid Catalyzed ◽  
Reaction Media ◽  
Column Chromatographic

A simple, straightforward and efficient method has been developed for the synthesis of (E)-3-(arylimino)indolin-2-one derivatives and (E)-2-((4-methoxyphenyl)imino)- acenaphthylen-1(2H)-one. The synthesis of these biologically-significant scaffolds was achieved from the reactions of various substituted anilines and isatins or acenaphthaquinone, respectively, using commercially available, environmentally benign and naturally occurring organic acids such as mandelic acid or itaconic acid as catalyst in aqueous medium at room temperature. Mild reaction conditions, energy efficiency, good to excellent yields, environmentally benign conditions, easy isolation of products, no need of column chromatographic separation and the reusability of reaction media are some of the significant features of the present protocol.

Insights into the Solubility of Carbon Dioxide in Grafted Mesoporous Silica for the Catalytic Synthesis of Cyclic Carbonates by Nanoconfinement

2021 ◽  
Author(s):  
Shahab Boroun ◽  
Abolfazl Alizadeh Sahraei ◽  
Abdol Hadi Mokarizadeh ◽  
Houshang Alamdari ◽  
Frédéric-Georges Fontaine ◽  
...  
Keyword(s):  
Carbon Dioxide ◽  
Mesoporous Silica ◽  
Catalytic Synthesis ◽  
Cyclic Carbonates

C3-symmetric zinc complexes as sustainable catalysts for transforming carbon dioxide into mono- and multi-cyclic carbonates

2021 ◽  
Vol 280 ◽  
pp. 119395
Author(s):  
Kanagaraj Naveen ◽  
Hoon Ji ◽  
Tea Soon Kim ◽  
Dongwoo Kim ◽  
Deug-Hee Cho
Keyword(s):  
Carbon Dioxide ◽  
Zinc Complexes ◽  
Cyclic Carbonates
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