A PROPOSED MULTI-BEAM X-RAY MONOCHROMATOR FOR SYNCHROTRON RADIATION : THEORETICAL CONSIDERATIONS

1987 ◽  
Vol 48 (C9) ◽  
pp. C9-75-C9-78
Author(s):  
C.-M. LO ◽  
S.-L. CHANG
Author(s):  
B. Jouffrey ◽  
D. Dorignac ◽  
A. Bourret

Since the early works on GP zones and the model independently proposed by Preston and Guinier on the first steps of precipitation in supersaturated solid solution of aluminium containing a few percent of copper, many works have been performed to understand the structure of different stages in the sequence of precipitation.The scheme which is generally admitted can be drawn from a work by Phillips.In their original model Guinier and Preston analysed a GP zone as composed of a single (100) copperrich plane surrounded by aluminum atomic planes with a slightly shorter distance from the original plane than in the solid solution.From X-ray measurements it has also been shown that GP1 zones were not only copper monolayer zones. They could be up to a few atomic planes thick. Different models were proposed by Guinier, Gerold, Toman. Using synchrotron radiation, proposals have been recently made.


1987 ◽  
Vol 48 (C1) ◽  
pp. C1-175-C1-181
Author(s):  
S. AHMAD ◽  
M. OHTOMO ◽  
R. W. WHITWORTH

1987 ◽  
Vol 48 (C9) ◽  
pp. C9-91-C9-94
Author(s):  
M. GRIONI ◽  
F. SCHAEFERS ◽  
J. B. GOEDKOOP ◽  
J. C. FUGGLE ◽  
J. L. WOOD ◽  
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Keyword(s):  

1976 ◽  
Vol 31 (6) ◽  
pp. 737-748 ◽  
Author(s):  
Karl-Heinz Tytko

Possible structures and the pertinent reaction pathways for the polymetalate ion present in a slightly soluble polymetalate having the analytical formula A2O · 2 MOs have been derived on the basis of theoretical considerations. Structure and kind of combination of the tetrameric units of one of the possibilities are in agreement with the results of X-ray structure analyses. First the previously proposed planar tetrametalate ion [M4O12(OH)4]4--is formed by stepwise aggregation according to an addition mechanism. This species undergoes a rearrangement of the coordination sphere of two of the M atoms and is then subject to a polycondensation resulting in a polytetrametalate chain, [M4O144-]n.


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