The role of ocean-atmosphere exchange in the global mercury cycle

2003 ◽  
Vol 107 ◽  
pp. 835-838 ◽  
Author(s):  
R. P. Mason ◽  
F. J.G. Laurier ◽  
L. Whalin ◽  
G.-R. Sheu
Elements ◽  
2020 ◽  
Vol 16 (3) ◽  
pp. 191-196 ◽  
Author(s):  
Christopher T. Reinhard ◽  
Noah J. Planavsky

The redox state of Earth’s atmosphere has undergone a dramatic shift over geologic time from reducing to strongly oxidizing, and this shift has been coupled with changes in ocean redox structure and the size and activity of Earth’s biosphere. Delineating this evolutionary trajectory remains a major problem in Earth system science. Significant insights have emerged through the application of redox-sensitive geochemical systems. Existing and emerging biogeochemical modeling tools are pushing the limits of the quantitative constraints on ocean–atmosphere redox that can be extracted from geochemical tracers. This work is honing our understanding of the central role of Earth’s biosphere in shaping the long-term redox evolution of the ocean–atmosphere system.


2021 ◽  
Author(s):  
Sem Vijverberg ◽  
Dim Coumou

<p>Heatwaves can have devastating impact on society and reliable early warnings at several weeks lead time are needed. Heatwaves are often associated with quasi-stationary Rossby waves, which interact with sea surface temperature (SST). Previous studies showed that north-Pacific SST can provide long-lead predictability for eastern U.S. temperature, moderated by an atmospheric Rossby wave. The exact mechanisms, however, are not well understood. Here we analyze Rossby waves associated with heatwaves in western and eastern US. Causal inference analyses reveal that both waves are characterized by positive ocean-atmosphere feedbacks at synoptic timescales, amplifying the waves. However, this positive feedback on short timescales is not the causal mechanism that leads to a long-lead SST signal. Only the eastern US shows a long-lead causal link from SSTs to the Rossby wave. We show that the long-lead SST signal derives from low-frequency PDO variability, providing the source of eastern US temperature predictability. We use this improved physical understanding to identify more reliable long-lead predictions. When, at the onset of summer, the Pacific is in a pronounced PDO phase, the SST signal is expected to persist throughout summer. These summers are characterized by a stronger ocean-boundary forcing, thereby more than doubling the eastern US temperature forecast skill, providing a temporary window of enhanced predictability.</p>


2010 ◽  
Vol 37 (1-2) ◽  
pp. 1-17 ◽  
Author(s):  
R. Krishnan ◽  
Suchithra Sundaram ◽  
P. Swapna ◽  
Vinay Kumar ◽  
D. C. Ayantika ◽  
...  

2017 ◽  
Vol 17 (18) ◽  
pp. 11313-11329 ◽  
Author(s):  
Stefanie Falk ◽  
Björn-Martin Sinnhuber ◽  
Gisèle Krysztofiak ◽  
Patrick Jöckel ◽  
Phoebe Graf ◽  
...  

Abstract. Very short-lived substances (VSLS) contribute as source gases significantly to the tropospheric and stratospheric bromine loading. At present, an estimated 25 % of stratospheric bromine is of oceanic origin. In this study, we investigate how climate change may impact the ocean–atmosphere flux of brominated VSLS, their atmospheric transport, and chemical transformations and evaluate how these changes will affect stratospheric ozone over the 21st century. Under the assumption of fixed ocean water concentrations and RCP6.0 scenario, we find an increase of the ocean–atmosphere flux of brominated VSLS of about 8–10 % by the end of the 21st century compared to present day. A decrease in the tropospheric mixing ratios of VSLS and an increase in the lower stratosphere are attributed to changes in atmospheric chemistry and transport. Our model simulations reveal that this increase is counteracted by a corresponding reduction of inorganic bromine. Therefore the total amount of bromine from VSLS in the stratosphere will not be changed by an increase in upwelling. Part of the increase of VSLS in the tropical lower stratosphere results from an increase in the corresponding tropopause height. As the depletion of stratospheric ozone due to bromine depends also on the availability of chlorine, we find the impact of bromine on stratospheric ozone at the end of the 21st century reduced compared to present day. Thus, these studies highlight the different factors influencing the role of brominated VSLS in a future climate.


2021 ◽  
Author(s):  
Sebastian Landwehr ◽  
Michele Volpi ◽  
F. Alexander Haumann ◽  
Charlotte M. Robinson ◽  
Iris Thurnherr ◽  
...  

Abstract. The Southern Ocean is a critical component of Earth’s climate system, but its remoteness makes it challenging to develop a holistic understanding of its processes from the small to the large scale. As a result, our knowledge of this vast region remains largely incomplete. The Antarctic Circumnavigation Expedition (ACE, austral summer 2016/2017) surveyed a large number of variables describing the dynamic state of the ocean and the atmosphere, the freshwater cycle, atmospheric chemistry, ocean biogeochemistry and microbiology. This circumpolar cruise included visits to twelve remote islands, the marginal ice zone, and the Antarctic coast. Here, we use 111 of the observed variables to study the latitudinal gradients, seasonality, shorter term variations, the geographic setting of environmental processes, and interactions between them over the duration of 90 days. To reduce the dimensionality and complexity of the dataset and make the relations between variables interpretable, we applied a sparse Principal Component Analysis (sPCA), which describes environmental processes through 14 latent variables. To derive a robust statistical perspective on these processes and to estimate the uncertainty in the sPCA decomposition, we have developed a bootstrap approach. We identified temporal patterns from diurnal to seasonal cycles, as well as geographical gradients and “hotspots” of interaction. Our results establish connections of oceanic, atmospheric, biological and terrestrial processes in an innovative way, while confirming many well known relations of the Southern Ocean system. More specifically, we identify: the important role of the oceanic circulations, frontal zones, and islands in shaping the nutrient availability that controls biological community composition and productivity; that sea ice predominantly controls sea water salinity, dampens the wave field, and is associated with increased phytoplankton growth and net community productivity possibly due to iron fertilization and reduced light limitation; and clear regional patterns of aerosol characteristics emerged, stressing the role of the sea state, atmospheric chemical processing, as well as source processes near “hotspots” for the availability of cloud condensation nuclei and hence cloud formation. A set of key variables and their combinations, such as the difference between the air and sea surface temperature, atmospheric pressure, sea surface height, geostrophic currents, upper ocean layer light intensity, surface wind speed and relative humidity, played an important role in the majority of latent variables, highlighting their importance for a large variety of processes and the necessity for Earth System Models to represent them adequately. In conclusion, our study highlights the use of sPCA to identify key ocean-atmosphere interactions across physical, chemical, and biological processes and their associated spatio-temporal scales. The sPCA processing code is available as open-access and we believe that our approach is widely applicable to other environmental field studies.


2003 ◽  
Vol 16 (6) ◽  
pp. 951-968 ◽  
Author(s):  
Andrew M. Moore ◽  
Jérôme Vialard ◽  
Anthony T. Weaver ◽  
David L. T. Anderson ◽  
Richard Kleeman ◽  
...  

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