Relaxation dynamics in confined glasses

2000 ◽  
Vol 10 (PR7) ◽  
pp. Pr7-227-Pr7-232 ◽  
Author(s):  
B. Jérôme ◽  
E. Cecchetto ◽  
N. R. de Souza ◽  
A. L. Demirel
Keyword(s):  
1992 ◽  
Author(s):  
Margarita Mihailidi ◽  
Qirong Xing ◽  
Kwong M. Yoo ◽  
Robert R. Alfano
Keyword(s):  

2021 ◽  
Vol 154 (8) ◽  
pp. 084201
Author(s):  
Elisa Fresch ◽  
Nicola Peruffo ◽  
Mariachiara Trapani ◽  
Massimiliano Cordaro ◽  
Giovanni Bella ◽  
...  

Author(s):  
Branislav Milovanović ◽  
Jurica Novak ◽  
Mihajlo Etinski ◽  
Wolfgang Domcke ◽  
Nadja Doslic

Despite many studies, the mechanisms of nonradiative relaxation of uracil in the gas phase and in aqueous solution are still not fully resolved. Here we combine theoretical UV absorption spectroscopy...


2007 ◽  
Vol 126 (23) ◽  
pp. 234707 ◽  
Author(s):  
Ádám Madarász ◽  
Peter J. Rossky ◽  
László Turi

2021 ◽  
Vol 154 (14) ◽  
pp. 144504
Author(s):  
Xiao Jin ◽  
Zijing Li ◽  
Yingdan Liu ◽  
Shidong Feng ◽  
Li-Min Wang

Gels ◽  
2021 ◽  
Vol 7 (2) ◽  
pp. 71
Author(s):  
Takuro Taniguchi ◽  
Kenji Urayama

We investigated the linear dynamic viscoelasticity of dual cross-link (DC) poly(vinyl alcohol) (PVA) (DC-PVA) hydrogels with permanent and transient cross-links. The concentrations of incorporated borate ions to form transient cross-links in the DC-PVA hydrogels (CBIN) were determined by the azomethine-H method. The dynamic viscoelasticity of the DC-PVA hydrogel cannot be described by a simple sum of the dynamic viscoelasticity of the PVA gel with the same permanent cross-link concentration and the PVA aqueous solution with the same borate ion concentration (CB = CBIN) as in the DC-PVA gel. The DC-PVA hydrogel exhibited a considerably higher relaxation strength, indicating that the introduction of permanent cross-links into temporary networks increases the number of viscoelastic chains with finite relaxation times. In contrast, the relaxation frequency (ωc) (given by the frequency at the maximum of loss modulus) for the DC-PVA hydrogel was slightly lower but comparable to that for a dilute PVA solution with the same CB. This signifies that the relaxation dynamics of the DC-PVA hydrogels is essentially governed by the lifetime of an interchain transient cross-link (di-diol complex of boron). The effect of permanent cross-linking on the relaxation dynamics was observed in the finite broadening of the relaxation-time distribution in the long time region.


Soft Matter ◽  
2021 ◽  
Author(s):  
Simon Stuij ◽  
Hannah Jonas ◽  
Zhe Gong ◽  
Stefano Sacanna ◽  
Tom Kodger ◽  
...  

The viscoelastic properties of filaments and biopolymers play a crucial role in soft and biological materials from biopolymer networks to novel synthetic metamaterials. Colloidal particles with specific valency allow mimicking...


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