scholarly journals In Situ XAS Investigations of Chemical Oscillations in the Oxidation of Co on Supported Pd Catalysts

1997 ◽  
Vol 7 (C2) ◽  
pp. C2-731-C2-733 ◽  
Author(s):  
T. Ressler ◽  
M. Hagelstein ◽  
U. Hatje ◽  
W. Metz
Author(s):  
Adam Hugh Clark ◽  
Huw Marchbank ◽  
David Thompsett ◽  
Janet Fisher ◽  
Alessandro Longo ◽  
...  

The effect of Pd loading on the redox characteristics of ceria was examined using in situ Pd K-edge XAS, Ce L3-edge XAS and in situ X-ray diffraction techniques. Analysis of...


2011 ◽  
Vol 133 (11) ◽  
pp. 3921-3930 ◽  
Author(s):  
Sven Reimann ◽  
Jan Stötzel ◽  
Ronald Frahm ◽  
Wolfgang Kleist ◽  
Jan-Dierk Grunwaldt ◽  
...  

2013 ◽  
Vol 20 (02) ◽  
pp. 1350013 ◽  
Author(s):  
CUN WEN ◽  
YI LIU ◽  
YUN GUO ◽  
YANQIN WANG ◽  
GUANZHONG LU

The effects of pretreating atmospheres ( H2 , O2 and Ar ) on the activity for CO oxidation and Pd dispersion of Pd/Pr6O11 catalyst were investigated. The result shows after the Pd/Pr6O11 catalyst was pretreated by hydrogen or oxygen at 550°C, its catalytic activity for CO oxidation can obviously increase, and the activity of H2 -pretreated catalyst is superior to that of O2 -pretreated catalyst, which is attributed to an increase of Pd dispersion. The catalyst pretreated by Ar behaves the worst catalytic activity for CO oxidation. The results of CO pulse, CO chemisorption and in situ DRIFT testing indicate that the surface species (hydroxyl species or active oxygen species) generated during pretreating processes can prevent Pd particles from immigrating and sintering, resulting in an increase of the Pd dispersion on the surface of support.


2014 ◽  
Vol 934 ◽  
pp. 60-64 ◽  
Author(s):  
Ling Niao Kong ◽  
Ya Ru Huang ◽  
Yin Jun Fang

Carbon nanotube (CNT) and activated carbon (AC)-supported Pd catalysts have been prepared by impregnation and reduction-precipitation method using chloropalladate acid as metal precursor. The catalytic performance for phenol in-situ hydrogenation was evaluated under 493 K, 3.5MPa. The results show that Pd/CNTs catalyst has higher selective for phenol in-situ hydrogenation to cyclohexanone. The catalysts have been characterised by CO-TPD and TEM. The mesoporosity structure and inner hollow cavities of Pd/CNTs catalyst are responsible for the distinguished properties.


2013 ◽  
Vol 132-133 ◽  
pp. 511-518 ◽  
Author(s):  
Atsushi Satsuma ◽  
Kaoru Osaki ◽  
Masatoshi Yanagihara ◽  
Junya Ohyama ◽  
Kenichi Shimizu

2021 ◽  
pp. 111491
Author(s):  
Camila A. Teles ◽  
Priscilla M. de Souza ◽  
Raimundo C. Rabelo-Neto ◽  
Alejandra Teran ◽  
Gary Jacobs ◽  
...  

2007 ◽  
Vol 111 (17) ◽  
pp. 6447-6453 ◽  
Author(s):  
N. Seshu Babu ◽  
N. Lingaiah ◽  
Rajesh Gopinath ◽  
P. Siva Sankar Reddy ◽  
P. S. Sai Prasad

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