scholarly journals Effect of second harmonic and second‐order intermodulation on third‐order passive intermodulation

2021 ◽  
Author(s):  
Qiuyan Jin ◽  
Quanyuan Feng
Keyword(s):  
Second Harmonic ◽  
Second Order ◽  
Third Order ◽  
Passive Intermodulation

Quadratic Electro-Optical Characterization of Molecular Nonlinear optical Materials

1987 ◽  
Vol 109 ◽  
Author(s):  
John C. Luong ◽  
N. F. Borrelli ◽  
A. R. Olszeuski
Keyword(s):  
Optical Materials ◽  
Nonlinear Optical ◽  
Second Harmonic ◽  
Low Frequency ◽  
Second Order ◽  
Third Order ◽  
Kerr Coefficient ◽  
Molecular Compounds ◽  
Order Susceptibility

ABSTRACTA convenient method of measuring the nonlinear optical properties of molecular compounds is described. The method involves measuring the quadratic electro-optical coefficient of a polymer composite containing a variable concentration of the candidate NLO material. The X(3) (ω) value obtained by this low-frequency Kerr measurement, after local-field corrections, can be compared to the nonresonant third-order susceptibility measured by degenerate-four-wave-mixing technique on selective samples. We find that the choice of the polymer matrix dictates the contribution of second-order susceptibility to the Kerr coefficient. Therefore, our method can also be extended to the measurement of second-order susceptibility, analogous to the technique of field-induced second-harmonic-generation.

Bulk Contributions Modulate the Sum-Frequency Generation Spectra of Interfacial Water on Model Sea-Spray Aerosols

2018 ◽  
Author(s):  
Sandeep K. Reddy ◽  
Raphael Thiraux ◽  
Bethany A. Wellen Rudd ◽  
Lu Lin ◽  
Tehseen Adel ◽  
...  
Keyword(s):  
Single Layer ◽  
Sum Frequency Generation ◽  
Second Order ◽  
Interfacial Structure ◽  
Sea Spray ◽  
Third Order ◽  
Systematic Analysis ◽  
Sum Frequency ◽  
Structure Of Water ◽  
Frequency Generation

Vibrational sum-frequency generation (vSFG) spectroscopy is used to determine the molecular structure of water at the interface of palmitic acid monolayers. Both measured and calculated spectra display speci c features due to third-order contributions to the vSFG response which are associated with nite interfacial electric potentials. We demonstrate that theoretical modeling enables to separate the third-order contributions, thus allowing for a systematic analysis of the strictly surface-sensitive, second-order component of the vSFG response. This study provides fundamental, molecular-level insights into the interfacial structure of water in a neutral surfactant system with relevance to single layer bio-membranes and environmentally relevant sea-spray aerosols. These results emphasize the key role that computer simulations can play in interpreting vSFG spectra and revealing microscopic details of water at complex interfaces, which can be difficult to extract from experiments due to the mixing of second-order, surface-sensitive and third-order, bulk-dependent contributions to the vSFG response.

Evidence for general base catalysis by protic solvents in a kinetic study of alcoholyses and hydrolyses of 1-(phenoxycarbonyl)pyridinium ions under both solvolytic and non-solvolytic conditions

2009 ◽  
Vol 74 (1) ◽  
pp. 43-55 ◽  
Author(s):  
Dennis N. Kevill ◽  
Byoung-Chun Park ◽  
Jin Burm Kyong
Keyword(s):  
Second Order ◽  
Base Catalysis ◽  
Substitution Reactions ◽  
Third Order ◽  
Methoxy Derivative ◽  
First Order ◽  
General Base ◽  
Protic Solvents ◽  
Kinetics Of ◽  
Pyridinium Ions

The kinetics of nucleophilic substitution reactions of 1-(phenoxycarbonyl)pyridinium ions, prepared with the essentially non-nucleophilic/non-basic fluoroborate as the counterion, have been studied using up to 1.60 M methanol in acetonitrile as solvent and under solvolytic conditions in 2,2,2-trifluoroethan-1-ol (TFE) and its mixtures with water. Under the non- solvolytic conditions, the parent and three pyridine-ring-substituted derivatives were studied. Both second-order (first-order in methanol) and third-order (second-order in methanol) kinetic contributions were observed. In the solvolysis studies, since solvent ionizing power values were almost constant over the range of aqueous TFE studied, a Grunwald–Winstein equation treatment of the specific rates of solvolysis for the parent and the 4-methoxy derivative could be carried out in terms of variations in solvent nucleophilicity, and an appreciable sensitivity to changes in solvent nucleophilicity was found.

scholarly journals Spectral Broadening in a Continuously Pumped Singly Resonant Second-Harmonic Cavity

2021 ◽  
Vol 11 (15) ◽  
pp. 7122
Author(s):  
Simona Mosca ◽  
Tobias Hansson ◽  
Maria Parisi
Keyword(s):  
Continuous Wave ◽  
Frequency Comb ◽  
Second Harmonic ◽  
Input Power ◽  
Second Order ◽  
Optical Frequency ◽  
Frequency Combs ◽  
Research Areas ◽  
Mixed Regime ◽  
Wide Range

Optical frequency comb synthesizers with a wide spectral range are an essential tool for many research areas such as spectroscopy, precision metrology, optical communication, and sensing. Recent studies have demonstrated the direct generation of frequency combs, via second-order processes, that are centered on two different spectral regions separated by an octave. Here, we present the capability of optical quadratic frequency combs for broad-bandwidth spectral emission in unexplored regimes. We consider comb formation under phase-matched conditions in a continuous-wave pumped singly resonant second-harmonic cavity, with large intracavity power and control of the detuning over several cavity line widths. The spectral analysis reveals quite distinctive sidebands that arise far away from the pump, singularly or in a mixed regime together with narrowband frequency combs. Notably, by increasing the input power, the optical frequency lines evolve into widely spaced frequency clusters, and at maximum power, they appear in a wavelength range spanning up to 100 nm. The obtained results demonstrate the power of second-order nonlinearities for direct comb production within a wide range of pump wavelengths.

scholarly journals A Molecular Architectural Approach to Second-Order Nonlinear Optical Materials

1995 ◽  
Vol 392 ◽  
Author(s):  
Xiaoguang Yang ◽  
Duncan McBranch ◽  
Basil Swanson ◽  
Dequan Li
Keyword(s):  
Nonlinear Optical ◽  
Second Harmonic ◽  
Fused Silica ◽  
Second Order ◽  
Nonlinear Susceptibility ◽  
Design And Synthesis ◽  
Fundamental Wavelength ◽  
Assembled Monolayers ◽  
Methylene Groups ◽  
Nlo Chromophores

AbstractThe design and synthesis of a family of calix[4]arene-based nonlinear optical (NLO) chromophores are discussed. The calixarene chromophores are macrocyclic compounds consisting of four simple D-π-A units bridged by methylene groups. These molecules were synthesized such that four D-π-A units of the calix[4]arene were aligned along the same direction with the calixarene in a cone conformation. These nonlinear optical super-chromophores were subsequently fabricated into covalently bound self-assembled monolayers on the surfaces of fused silica and silicon. Spectroscopic second harmonic generation (SHG) measurements were carried out to determine the absolute value of the dominant element of the second-order nonlinear susceptibility, d33, and the average molecular alignment, ψ. We find a value of d33 = 60 pm/V at a fundamental wavelength of 890 nm, and ψ˜ 36° with respect to the surface normal.

Panicle, spikelet, and floret development in orchardgrass (Dactylis glomerata)

1993 ◽  
Vol 71 (4) ◽  
pp. 523-532 ◽  
Author(s):  
Joanna Fraser ◽  
Eric G. Kokko
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Unique Feature ◽  
Dactylis Glomerata ◽  
Bilateral Symmetry ◽  
Second Order ◽  
Third Order ◽  
First Order ◽  
Lateral Branches ◽  
Scanning Electron

The initial stages of panicle, spikelet, and floret development in field-grown 'Kay' orchardgrass were examined using scanning electron microscopy. Spikelets arose from a complex multilevelled sequence of initiation from branch apices. Spikelets developed indirectly in a two-tiered progression: (i) an acropetal and basipetal sequence of first order, second-order, and third-order inflorescence apices, and (ii) an acropetal development within subclusters of higher-order lateral branch inflorescence apices. The panicle had the unique feature of dorsiventrality as well as bilateral symmetry. The basal apex from first-order, second-order, or third-order apices developed on the same side of the main axis as the first-order apex. The two glumes subtending each spikelet primordium developed alternately and acropetally. Development and initiation of florets within spikelets was basipetal within the panicle, basipetal within clusters and subclusters of spikelets on lateral branches, and acropetal within spikelets. Within florets, paleas developed later than lemmas. Key words: Dactylis glomerata, cocksfoot, scanning electron microscopy, development, panicle.

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