scholarly journals Roles of UV light strength and auxiliary electric field in the photocatalytic degradation effect of organic contaminant

High Voltage ◽  
2019 ◽  
Vol 4 (2) ◽  
pp. 113-121 ◽  
Author(s):  
Lin YaoYu ◽  
Ma YanXiang ◽  
Bian XingMing ◽  
Sun PengCheng
Materials ◽  
2021 ◽  
Vol 14 (14) ◽  
pp. 3816
Author(s):  
Xiaojie Li ◽  
Xin Li ◽  
Pei Zuo ◽  
Xiaozhe Chen ◽  
Misheng Liang ◽  
...  

TiO2 is popular in photocatalytic degradation dye pollutants due to its abundance and its stability under photochemical conditions. Au loaded TiO2 can achieve efficient absorption of visible light and deal with the problem of low conversion efficiency for solar energy of TiO2. This work presents a new strategy to prepare Au nanoparticles-loaded TiO2 composites through electric−field−assisted temporally−shaped femtosecond laser liquid-phase ablation of Au3+ and amorphous TiO2. By adjusting the laser pulse delay and electric field parameters, gold nanoparticles with different structures can be obtained, such as nanospheres, nanoclusters, and nanostars (AuNSs). AuNSs can promote the local crystallization of amorphous TiO2 in the preparation process and higher free electron density can also be excited to work together with the mixed crystalline phase, hindering the recombination between carriers and holes to achieve efficient photocatalytic degradation. The methylene blue can be effectively degraded by 86% within 30 min, and much higher than the 10% of Au nanoparticles loaded amorphous TiO2. Moreover, the present study reveals the crystallization process and control methods for preparing nanoparticles by laser liquid ablation, providing a green and effective new method for the preparation of high-efficiency photocatalytic materials.


2020 ◽  
Vol 9 (1) ◽  
pp. 922-933
Author(s):  
Qing’e Wang ◽  
Kai Zheng ◽  
Huanan Yu ◽  
Luwei Zhao ◽  
Xuan Zhu ◽  
...  

AbstractOil leak from vehicles is one of the most common pollution types of the road. The spilled oil could be retained on the surface and spread in the air voids of the road, which results in a decrease in the friction coefficient of the road, affects driving safety, and causes damage to pavement materials over time. Photocatalytic degradation through nano-TiO2 is a safe, long-lasting, and sustainable technology among the many methods for treating oil contamination on road surfaces. In this study, the nano-TiO2 photocatalytic degradation effect of road surface oil pollution was evaluated through the lab experiment. First, a glass dish was used as a substrate to determine the basic working condition of the test; then, a test method considering the impact of different oil erosion degrees was proposed to eliminate the effect of oil erosion on asphalt pavement and leakage on cement pavement, which led to the development of a lab test method for the nano-TiO2 photocatalytic degradation effect of oil pollution on different road surfaces.


Author(s):  
Shriram Pillapakkam ◽  
N. A. Musunuri ◽  
P. Singh

In this paper, we present a technique for freezing monolayers of micron and sub-micron sized particles onto the surface of a flexible thin film after the self-assembly of a particle monolayer on fluid-liquid interfaces has been improved by the process we have developed where an electric field is applied in the direction normal to the interface. Particles smaller than about 10 microns do not self-assemble under the action of lateral capillary forces alone since capillary forces amongst them are small compared to Brownian forces. We have overcome this problem by applying an electric field in the direction normal to the interface which gives rise to dipoledipole and capillary forces which cause the particles to arrange in a triangular pattern. The technique involves assembling the monolayer on the interface between a UV-curable resin and another liquid by applying an electric field, and then curing the resin by applying UV light. The monolayer becomes embedded on the surface of the solidified resin film.


2009 ◽  
Vol 172 (2-3) ◽  
pp. 1424-1429 ◽  
Author(s):  
G.L. Liu ◽  
D.W. Zhu ◽  
S.J. Liao ◽  
L.Y. Ren ◽  
J.Z. Cui ◽  
...  

2011 ◽  
Vol 11 (3) ◽  
pp. 253-257 ◽  
Author(s):  
Winarti Andayani ◽  
Agustin N M Bagyo

Degradation of humic acid in aqueous solution containing TiO2 coated on ceramics beads under irradiation of 254 nm UV light has been conducted in batch reactor. The aim of this experiment was to study photocatalytic degradation of humic acid in peat water. The irradiation of the humic acid in aqueous solution was conducted in various conditions i.e solely uv, in the presence of TiO2-slurry and TiO2 beads. The color intensity, humic acid residue, conductivity and COD (chemical oxygen demand) of the solution were analyzed before and after irradiation.  The compounds produced during photodegradation were identified using HPLC. The results showed that after photocatalytic degradation, the color intensity and the COD value of the solution decreased, while the conductivity of water increased indicating mineralization of the peat water occurred. In addition, oxalic acid as the product of degradation was observed.


Polymers ◽  
2020 ◽  
Vol 12 (1) ◽  
pp. 65 ◽  
Author(s):  
Bing-Yau Huang ◽  
Shuan-Yu Huang ◽  
Chia-Hsien Chuang ◽  
Chie-Tong Kuo

This paper proposes an effective approach to fabricate a blue phase liquid crystal (BPLC) microlens array based on a photoconductive film. Owing to the characteristics of photo-induced conducting polymer polyvinylcarbazole (PVK), in which conductivity depends on the irradiation of UV light, a progressive mask resulting in the variation of conductivity is adopted to produce the gradient distribution of the electric field. The reorientations of liquid crystals according to the gradient distribution of the electric field induce the variation of the refractive index. Thus, the incident light experiences the gradient distribution of the refractive index and results in the focusing phenomenon. The study investigates the dependence of lens performance on UV exposure time, the focal length of the lens, and focusing intensities with various incident polarizations. The BPLC microlens array exhibits advantages such as electrically tunability, polarization independence, and fast response time.


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