scholarly journals Hyperfine structure of [57Fe]iron in the Mössbauer spectrum of the high-potential iron protein from Chromatium

1970 ◽  
Vol 119 (2) ◽  
pp. 289-291 ◽  
Author(s):  
M. C. W. Evans ◽  
D. O. Hall ◽  
C. E. Johnson

The magnetic hyperfine structure observed in the 57Fe Mössbauer spectra of the high-potential iron protein from Chromatium shows that the iron atoms are inequivalent in pairs, with hyperfine fields of 121 and 90kG.

1984 ◽  
Vol 48 (349) ◽  
pp. 507-511 ◽  
Author(s):  
Enver Murad ◽  
Udo Schwertmann

AbstractParticle morphology can result in very pronounced effects of crystallinity on the Mössbauer spectra of lepidocrocite. Such effects can noticeably increase the quadrupole splitting of poorly crystallized paramagnetic lepidocrocites, making it necessary to fit two doublets of different quadrupole splittings to Mössbauer spectra of such samples, and may lower the onset of magnetic ordering from the bulk Néel temperature of 77 ±1 K to about 50 K.At 4.2 K, distributions of magnetic hyperfine fields with a limiting upper field of 460 kOe are observed. The contributions of lower fields to such distributions increase with decreasing crystallinity, producing asymmetrically broadened resonant lines.


1980 ◽  
Vol 104 (1) ◽  
pp. 289-296 ◽  
Author(s):  
Peter MIDDLETON ◽  
Dominic P. E. DICKSON ◽  
Charles E. JOHNSON ◽  
James D. RUSH

1975 ◽  
Vol 54 (4) ◽  
pp. 293-294 ◽  
Author(s):  
P. Boolchand ◽  
M. Tenhover ◽  
S. Jha ◽  
G. Langouche ◽  
B.B. Triplett ◽  
...  

2021 ◽  
Author(s):  
Natalia Kazak ◽  
Yurii V. Knyazev ◽  
Vyacheslav Zhandun ◽  
Juan Bartolomé ◽  
Ana Arauzo ◽  
...  

The ludwigite Co2FeBO5 has been studied experimentally using 57Fe Mössbauer spectroscopy and theoretically by means of the DFT+GGA calculations. The room-temperature Mössbauer spectra are composed of four quadrupole doublets corresponding...


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