Reactions of the ethyl radical. Part 9.—Addition, dismutation and metathesis with allyl ethyl ether and diallyl ether

1969 ◽  
Vol 65 (0) ◽  
pp. 763-774 ◽  
Author(s):  
D. G. L. James ◽  
G. E. Troughton
Keyword(s):  
Ethyl Ether ◽  
Ethyl Radical ◽  
Diallyl Ether

The effect of electrondonors on the polymerization kinetics of isoprene

1980 ◽  
Vol 45 (12) ◽  
pp. 3338-3346
Author(s):  
Miroslav Kašpar ◽  
Jiří Trekoval
Keyword(s):  
Induction Period ◽  
Ethyl Ether ◽  
Reaction Order ◽  
Propagation Rate ◽  
Reaction Scheme ◽  
Polymerization Kinetics ◽  
Polymerization Rate ◽  
Constant Concentration ◽  
Initial Concentration ◽  
Kinetics Of

The effect of small additions of 1-octene, butyl ethyl ether and triethylamine on the polymerization kinetics of isoprene (2-methyl-1,3-butadiene) in benzene initiated with butyllithium was investigated by employing the GLC analysis. The addition of 1-octane was reflected only in a shorter induction period of the reaction; the effect on the propagation rate was insignificant. With the increasing amount of butyl ethyl ether, the polymerization rate increases linearly, while the reaction order with respect to the concentration of triethylamine is variable and increases from 0.33 to 0.66 with the increasing concentration of the initiator. For a constant concentration of triethylamine, the reaction order with respect to the initial concentration of the initiator was found to vary considerably, reaching even negative values. A reaction scheme was suggested, taking into account the competition between two different solvates of alkyllithium.

ChemInform Abstract: THE THERMAL DECOMPOSITION OF METHYLTITANIUM TRICHLORIDE IN ETHYL ETHER

1978 ◽  
Vol 9 (43) ◽  
Author(s):  
D. DONG ◽  
S. C. V. STEVENS ◽  
J. D. MCCOWAN ◽  
M. C. BAIRD
Keyword(s):  
Thermal Decomposition ◽  
Ethyl Ether

scholarly journals Synthesis of tert-amyl Ethyl Ether for Gasoline Additive

2015 ◽  
Vol 75 ◽  
pp. 3265-3270 ◽  
Author(s):  
Zhao Lei ◽  
Hang Zhang ◽  
Jing-Jun Liu ◽  
Bo-Lun Yang
Keyword(s):  
Ethyl Ether ◽  
Gasoline Additive
Sign in / Sign up

Export Citation Format

Share Document