scholarly journals Activated complex theory applied to the thermal decomposition of solids

1964 ◽  
Vol 60 ◽  
pp. 1902 ◽  
Author(s):  
Robert D. Shannon
Keyword(s):  
Thermal Decomposition ◽  
Complex Theory ◽  
Activated Complex

Studies on metal hydroxy compounds. IX. Kinetics of thermal decomposition of twelve copper halide derivatives

1969 ◽  
Vol 47 (20) ◽  
pp. 3915-3918 ◽  
Author(s):  
P. Ramamurthy ◽  
E. A. Secco
Keyword(s):  
Thermal Decomposition ◽  
Copper Hydroxide ◽  
Copper Halide ◽  
Complex Theory ◽  
Kinetics Of Thermal Decomposition ◽  
Hydroxy Compounds ◽  
Kinetics Of ◽  
Derivatives Of ◽  
Activated Complex

The kinetics of the thermal decomposition of 12 halide (F, Cl, Br, I) derivatives of copper hydroxide are reported. The kinetic results and their interpretation in terms of activated complex theory are compared with the results and interpretation of the thermal decomposition of zinc and cadmium hydroxyhalides.

Studies on metal hydroxy compounds. VI. Kinetics of thermal decomposition of zinc and cadmium halide (Cl, F) derivatives

1969 ◽  
Vol 47 (12) ◽  
pp. 2181-2184 ◽  
Author(s):  
P. Ramamurthy ◽  
E. A. Secco
Keyword(s):  
Thermal Decomposition ◽  
Reaction Mechanism ◽  
Molecular Rotation ◽  
Complex Theory ◽  
Kinetics Of Thermal Decomposition ◽  
Translational Mode ◽  
Hydroxy Compounds ◽  
Kinetics Of ◽  
Activated Complex

Kinetics of thermal decomposition of zinc and cadmium hydroxides along with their halide (Cl, F) derivatives are reported. The kinetic results are discussed in terms of the appropriate reaction mechanism. The rates are also discussed using activated complex theory in a manner outlined by Cordes (9) where the effect of molecular rotation in both the reactants and the activated complex is considered. Furthermore, the abnormally high preexponential factors are speculated to have their origin in an active translational mode on the surface.

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