Spectroscopic studies of solvent systems. Part 1.—Solutions of AlCl3in SOCl2

1963 ◽  
Vol 59 (0) ◽  
pp. 594-598 ◽  
Author(s):  
D. A. Long ◽  
R. T. Bailey
1993 ◽  
Vol 71 (11) ◽  
pp. 1834-1840 ◽  
Author(s):  
Mark L. O'Neill ◽  
Peeter Kruus ◽  
Robert C. Burk

Spectroscopic studies of the compound 2-nitroanisole in supercritical fluids CO2 and N2O show that π* values vary linearly with density. The solubility trends in these single component supercritical fluid solvents qualitatively followed the trends in solvent power predicted from π*. However, the relative solvent power predicted for CO2 and N2O based on π* resulted in an opposite order to what was determined experimentally through solubility measurements. The π* parameter may be of some use for solubility prediction if only a limited set of solute–solvent systems are considered. Measurements of π*, especially those in binary supercritical fluid solvents, suggest that π* could be a valuable tool for probing the solute-organized cybotactic region.


2001 ◽  
Vol 40 (21) ◽  
pp. 5324-5333 ◽  
Author(s):  
Hartmut Drechsel ◽  
Marina Fiallo ◽  
Arlette Garnier-Suillerot ◽  
Berthold F. Matzanke ◽  
Volker Schünemann

1987 ◽  
Vol 84 ◽  
pp. 443-448 ◽  
Author(s):  
Teresa Kowalik ◽  
Brigitte Decock-Le Reverend ◽  
Claude Loucheux ◽  
Damien Ficheux ◽  
Henryk Kozlowski

1980 ◽  
Vol 41 (C1) ◽  
pp. C1-187-C1-188 ◽  
Author(s):  
G. P. Gupta ◽  
J. A. Baines ◽  
D. M. Cooper ◽  
D. P.E. Dickson ◽  
C. E. Johnson

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