Diffusion-controlled termination in free radical copolymerization

1962 ◽  
Vol 58 ◽  
pp. 2049 ◽  
Author(s):  
J. N. Atherton ◽  
A. M. North
Keyword(s):  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Diffusion Controlled

scholarly journals Modeling of the Free Radical Copolymerization Kinetics of n-Butyl Acrylate, Methyl Methacrylate and 2-Ethylhexyl Acrylate Using PREDICI®

Processes ◽  
2019 ◽  
Vol 7 (7) ◽  
pp. 395 ◽  
Author(s):  
Javier A. Gómez-Reguera ◽  
Eduardo Vivaldo-Lima ◽  
Vida A. Gabriel ◽  
Marc A. Dubé
Keyword(s):  
Free Radical ◽  
Methyl Methacrylate ◽  
Butyl Acrylate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Diffusion Controlled ◽  
Wide Range ◽  
Kinetics Of ◽  
Global Parameters ◽  
Copolymerization Kinetics

Kinetic modeling of the bulk free radical copolymerizations of n-butyl acrylate (BA) and 2-ethylhexyl acrylate (EHA); methyl methacrylate (MMA) and EHA; as well as BA, MMA and EHA was performed using the software PREDICI®. Predicted results of conversion versus time, composition versus conversion, and molecular weight development are compared against experimental data at different feed compositions. Diffusion-controlled effects and backbiting for BA were incorporated into the model as they proved to be significant in these polymerizations. The set of estimated global parameters allows one to assess the performance of these copolymerization systems over a wide range of monomer compositions.

High-pressure free-radical copolymerization of ethene and 2-ethylhexyl acrylate

1996 ◽  
Vol 197 (12) ◽  
pp. 4119-4134 ◽  
Author(s):  
Michael Buback ◽  
Thomas Dröge ◽  
Alex Van Herk ◽  
Frank-Olaf Mähling
Keyword(s):  
High Pressure ◽  
Free Radical ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization

Free Radical Copolymerization of Ethylene with Vinyl Acetate under Mild Conditions

2017 ◽  
Vol 50 (9) ◽  
pp. 3516-3523 ◽  
Author(s):  
A. Zarrouki ◽  
E. Espinosa ◽  
C. Boisson ◽  
V. Monteil
Keyword(s):  
Free Radical ◽  
Vinyl Acetate ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization ◽  
Mild Conditions

Synthesis and characterization of hyperbranched associative polyacrylamide

RSC Advances ◽  
2016 ◽  
Vol 6 (45) ◽  
pp. 39522-39529 ◽  
Author(s):  
Wanfen Pu ◽  
Daijun Du ◽  
Rui Liu ◽  
Jiongyi Gu ◽  
Kewei Li ◽  
...  
Keyword(s):  
Free Radical ◽  
Radical Copolymerization ◽  
Synthesis And Characterization ◽  
Functional Monomer ◽  
Free Radical Copolymerization ◽  
Ultrafine Silica ◽  
Hyperbranched Polyamide

HDPAM was synthesized by water free-radical copolymerization based on functional hyperbranched polyamide-modified ultrafine silica as functional monomer.

Strain hardening and highly resilient hydrogels crosslinked by chain-extended reactive pseudo-polyrotaxane

RSC Advances ◽  
2014 ◽  
Vol 4 (100) ◽  
pp. 56791-56797 ◽  
Author(s):  
Yulin Cui ◽  
Mei Tan ◽  
Aidi Zhu ◽  
Mingyu Guo
Keyword(s):  
Free Radical ◽  
Strain Hardening ◽  
Radical Copolymerization ◽  
Free Radical Copolymerization

Hydrogels with obvious strain hardening and high resilience properties in both stretching and compressing processes are constructed by simple free-radical copolymerization of acrylamide and reactive pseudo-polyrotaxane.

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