The second virial coefficients, latent heats of vaporization and heats of formation of the lutidines

1960 ◽  
Vol 56 ◽  
pp. 959 ◽  
Author(s):  
J. D. Cox
1962 ◽  
Vol 15 (2) ◽  
pp. 190 ◽  
Author(s):  
GA Bottomley ◽  
IH Coopes

The second virial coefficients at two temperatures somewhat above room temperature have been determined for the three substances dimethyl sulphide, diethyl sulphide, and methyl ethyl sulphide by e precision differential compressibility method, and the numerical values compared with determinations by the indirect thermodynamic method using vapour specific heats and latent heats of evaporation.


2000 ◽  
Vol 65 (9) ◽  
pp. 1464-1470 ◽  
Author(s):  
Anatol Malijevský ◽  
Tomáš Hujo

The second and third virial coefficients calculated from the Bender equation of state (BEOS) are tested against experimental virial coefficient data. It is shown that the temperature dependences of the second and third virial coefficients as predicted by the BEOS are sufficiently accurate. We conclude that experimental second virial coefficients should be used to determine independently five of twenty constants of the Bender equation. This would improve the performance of the equation in a region of low-density gas, and also suppress correlations among the BEOS constants, which is even more important. The third virial coefficients cannot be used for the same purpose because of large uncertainties in their experimental values.


1971 ◽  
Vol 55 (5) ◽  
pp. 2071-2075
Author(s):  
Fouad Khoury ◽  
D. B. Robinson

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