Concentration and temperature dependence of diffusion coefficients for systems polymethyl acrylate and n-alkyl acetates

1960 ◽  
Vol 56 ◽  
pp. 424 ◽  
Author(s):  
Hiroshi Fujita ◽  
Akira Kishimoto ◽  
Kinya Matsumoto
1963 ◽  
Vol 8 (2) ◽  
pp. 168-169 ◽  
Author(s):  
Spencer L. Seager ◽  
Lyle R. Geertson ◽  
J. Calvin Giddings

2009 ◽  
Vol 283-286 ◽  
pp. 155-160
Author(s):  
Ivo Stloukal ◽  
Jiří Čermák

Self-diffusion of 110mAg has been investigated in fiber reinforced QE22 magnesium alloy matrix composite. Short Saffil fibers (97% -Al2O3 + 3% SiO2) were used as reinforcement. The diffusion measurements were carried out in the temperature interval 648 – 728 K by serial sectioning method. The volume diffusion coefficients Dv (alloy without reinforcement) and the effective diffusion coefficients Deff (alloy with reinforcement) were obtained by analysis of the penetration curves. The silver diffusion coefficient in the interface boundary matrix/Saffil Di was also estimated. The temperature dependence of volume diffusion coefficients Dv was compared with previous data measured using 65Zn in the same alloy and with literature data for Zn impurity diffusion in Mg single crystal. It was observed, that the temperature dependence of both Deff and Di was significantly non-linear in the measured temperature interval. This behavior supports previous observations with zinc diffusion in the same alloy.


1974 ◽  
Vol 29 (6) ◽  
pp. 957-958
Author(s):  
S. J. Larsson ◽  
P.-E. Eriksson

The diffusion coefficients of 65Zn and 115Cd in liquid Ga have been measured between 27° and 455 °C. The temperature dependence of D can be represented by a linear plot or by an Arrhenius representation with D0=2.1·10-4 cm2/s, Q=1.60 kcal/mol for Zn, and D0=2.3·10-4 cm2/s, Q=1.77 kcal/mol for Cd. An extrapolation to lower temperatures for Zn in Ga connects to the measurements by Belskii et al. The present results imply that for impurity diffusion in liquid Ga the effects of solute mass are more significant than valence effects.


1971 ◽  
Vol 49 (11) ◽  
pp. 1965-1967 ◽  
Author(s):  
Harry Watts

The diffusion coefficients in air of 1,1-dichloroethane, 1,1,1-trichloroethane, trichloroethylene, and tetrachloroethylene have been measured over a temperature range from room temperature to close to their boiling points by a rate of evaporation method.


1986 ◽  
Vol 1 (1) ◽  
pp. 202-204 ◽  
Author(s):  
Peter F. Green ◽  
Edward J. Kramer

The temperature dependence of the tracer diffusion coefficient D* of long deuterated polystyrene (d-PS) chains of molecular weight M>Mc, where Mc is the critical molecular weight for entanglement, diffusing into highly entangled PS matrices, each of molecular weight P = 2×107, is studied using forward recoil spectrometry. It is found that the temperature dependence of D*/T, reflected primarily in the monomeric friction coefficient, is accurately described by a Vogel equation. The constants that are used to fit these results are independent of M and are the same as those used to fit the temperature dependence of the zero shear rate viscosity of polystyrene.


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