The heterogeneous reaction between formic acid and nitrogen dioxide

1957 ◽  
Vol 53 ◽  
pp. 468 ◽  
Author(s):  
F. H. Pollard ◽  
K. A. Holbrook
2019 ◽  
Vol 1 (2-2) ◽  
Author(s):  
Mohd Jumain Jalil ◽  
Intan Suhada Azmi ◽  
Arif Aminuddin Ahmad Zulkifli ◽  
Mohamad Helmi Mohd Asbi

The epoxidized vegetables oils can be used a raw material for a broad range of products, from pharmaceutical and plastics to paint and adhesives. Epoxidation of oleic acid was carried out by using hydrogen peroxide as an oxygen donor and formic acid as an oxygen carrier in the presence of sulphuric acid act as catalyst. The crude oleic acid contained 75% oleic acid, 12.2% linoleic acid, 6.5% palmitic acid and 7.5% stearic acid, and had an iodine value of 98.99 g/100 g. The epoxidation of oleic acid with almost complete conversion of unsaturated carbon and negligible oxirane cleavage can be obtained by the in situ techniques. An analytical approach for the prediction of the partition coefficient for formic acid between oleic acid and water, dependent on temperature and composition, has been proposed.


2015 ◽  
Vol 119 (35) ◽  
pp. 9317-9324 ◽  
Author(s):  
Zhenyu Sun ◽  
Lingdong Kong ◽  
Xi Zhao ◽  
Xiaoxiao Ding ◽  
Hongbo Fu ◽  
...  

2021 ◽  
Vol 193 ◽  
pp. 110543
Author(s):  
Aurélie Marion ◽  
Julien Morin ◽  
Adrien Gandolfo ◽  
Elena Ormeño ◽  
Barbara D'Anna ◽  
...  

2016 ◽  
Vol 18 (14) ◽  
pp. 9367-9376 ◽  
Author(s):  
Zhenyu Sun ◽  
Lingdong Kong ◽  
Xiaoxiao Ding ◽  
Chengtian Du ◽  
Xi Zhao ◽  
...  

Acetaldehyde, glyoxal and acetic acid have a significant impact on the heterogeneous conversion of NO2 and the formation of nitrate and nitrite.


2012 ◽  
Vol 116 (42) ◽  
pp. 10390-10396 ◽  
Author(s):  
Ling-Yan Wu ◽  
Sheng-Rui Tong ◽  
Si-Qi Hou ◽  
Mao-Fa Ge

Nature ◽  
1956 ◽  
Vol 177 (4513) ◽  
pp. 799-800 ◽  
Author(s):  
F. H. POLLARD ◽  
K. A. HOLBROOK
Keyword(s):  

Chemosphere ◽  
2021 ◽  
pp. 132430
Author(s):  
Shideng Yuan ◽  
Shasha Liu ◽  
Yingzhe Du ◽  
Xueyu Wang ◽  
Heng Zhang ◽  
...  

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