The spectrophotometric determination of the ionization constants of a dibasic acid

1956 ◽  
Vol 52 ◽  
pp. 327 ◽  
Author(s):  
R. A. Robinson ◽  
A. K. Kiang
Author(s):  
V. I. Slovetskii ◽  
L. V. Okhlobystina ◽  
A. A. Fainzil'berg ◽  
A. I. Ivanov ◽  
L. I. Biryukova ◽  
...  

1988 ◽  
Vol 53 (2) ◽  
pp. 258-268 ◽  
Author(s):  
Brígida Santana ◽  
María J. Sánchez ◽  
Juan J. Arias ◽  
Francisco García-Montelongo

2-(2’-Thiazolylazo)-4,6-dimethylphenol (TADMP) and 2-(4’,5’-dimethyl-2’-thiazolylazo)-4,6-dimethylphenol (DMTADMP) have been synthesized and their ionization constants determined by spectrophotometric methods and graphical and numerical calculation methods. Both reagents form UO2R+ and UO2R2 complexes with uranium (TADMP: log β101 = 9.18 ± 0.02, log β102 = 17.64 ± 0.01; DMTADMP: log β101 = 8.38 ± 0.02, log β102 = 18.78 ± 0.14) in a 40% (v/v) ethanol-water medium at I = 0.25 (NaClO4). An extraction-spectrophotometric method for the determination of 1.35-9.45 ppm uranium based on its extraction into toluene with TADMP from a pH 6.5 buffered medium has been developed ( ε = 1.6 . 104 l mol-1 cm-1 at 580 nm), and applied to its determination in sulphuric acid leaching residues.


2008 ◽  
Vol 37 (6) ◽  
pp. 857-874 ◽  
Author(s):  
Jana Ehlerova ◽  
Liliana Trevani ◽  
Josef Sedlbauer ◽  
Peter Tremaine

2018 ◽  
Author(s):  
Xhulieta Hamiti ◽  
Ilirjana Boci ◽  
Pranvera Lazo

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