An attempted isotopic separation by fractional crystallisation

1941 ◽  
Vol 37 ◽  
pp. 587
Author(s):  
William J. C. Orr
Keyword(s):  
Fractional Crystallisation ◽  
Isotopic Separation

scholarly journals The Components of the Glacial Runoff of the Tsambagarav Massif from Stable Water Isotope Data

Geosciences ◽  
2019 ◽  
Vol 9 (7) ◽  
pp. 297 ◽  
Author(s):  
Dmitry V. Bantcev ◽  
Dmitry A. Ganyushkin ◽  
Kirill V. Chistyakov ◽  
Ilya V. Volkov ◽  
Alexey A. Ekaykin ◽  
...  
Keyword(s):  
Global Climate ◽  
Isotopic Analysis ◽  
Ice Formation ◽  
Northwestern Part ◽  
Glacial Ice ◽  
Main Method ◽  
Total Runoff ◽  
Glacial Runoff ◽  
Isotopic Separation ◽  
Main Components

The aim of this study was to determine the contribution of snow and glacial ice to the river fluxes, and to identify the type of ice formation in the Tsambagarav massif (the northwestern part of Mongolia). The main method for this study was isotopic analysis of water samples. The isotopic separation showed that the shares of the main components in the total runoff differed for different rivers of the massif. Alongside with that, glacial meltwater prevailed in all the investigated fluxes. The share of snow and firn in the meltwater coming from the surface of the large valley glaciers in the middle of the ablation season in 2017 changed by only 10%—from 20% to 30%. Thus, further reduction of glaciation caused by global climate change could significantly affect the water balance of the study area. The isotopic composition of glacial ice proves that its alimentation primarily comes from precipitation during the transitional seasons. Superimposed ice is not the basis for nourishment of the glaciers of the Tsambagarav massif.

scholarly journals Miocene and Pliocene Silicic Coromandel Volcanic Zone Tephras from ODP Site 1124-C: Petrogenetic Applications and Temporal Evolution

2021 ◽  
Author(s):  
◽  
Matthew Thomas Stevens
Keyword(s):  
Trace Element ◽  
Mantle Wedge ◽  
Major Element ◽  
Volcanic Glass ◽  
Fractional Crystallisation ◽  
Volcanic Zone ◽  
Arc Magmas ◽  
Glass Shard ◽  
Tephra Layers ◽  
Glass Shards

<p>The Coromandel Volcanic Zone (CVZ) was the longest-lived area of volcanism in New Zealand hosting the commencement of large explosive rhyolitic and ignimbrite forming eruptions. The NW trending Coromandel Peninsula is the subaerial remnant of the Miocene-Pliocene CVZ, which is regarded as a tectonic precursor to the Taupo Volcanic Zone (TVZ), currently the most dynamic and voluminous rhyolitic volcanic centre on Earth. This study presents new single glass shard major and trace element geochemical analyses for 72 high-silica volcanic tephra layers recovered from well-dated deep-sea sediments of the SW Pacific Ocean by the Ocean Drilling Program (ODP) Leg 181. ODP Site 1124, ~720 km south and east from the CVZ, penetrated sediments of the Rekohu Drift yielding an unprecedented record of major explosive volcanic eruptions owing to the favourable location and preservation characteristics at this site. This record extends onshore eruptive sequences of CVZ explosive volcanism that are obscured by poor exposure, alteration, and erosion and burial by younger volcanic deposits. Tephra layers recovered from Site 1124 are well-dated through a combination of biostratigraphic and palaeomagnetic methods allowing the temporal geochemical evolution of the CVZ to be reconstructed in relation to changes in the petrogenesis of CVZ arc magmas from ~ 10 to 2 Ma. This thesis establishes major and trace element geochemical "fingerprints" for all Site 1124-C tephras using well-established (wavelength dispersive electron probe microanalysis) and new (laser ablation inductively coupled plasma mass spectrometry) in situ single glass shard microanalytical techniques. Trace element analysis of Site 1124-C glass shards (as small as 20 um) demonstrate that trace element signatures offer a more specific, unequivocal characterisation for distinguishing (and potentially correlating) between tephras with nearly identical major element compositions. The Site 1124-C core contains 72 unaltered Miocene-Pliocene volcanic glass-shard-bearing laminae > 1 cm thick that correspond to 83 or 84 geochemical eruptive units. Revised eruptive frequencies based on the number of geochemical eruptive units identified represent at least one eruption every 99 kyr for the late Miocene and one per 74 kyr for the Pliocene. The frequency of tephra deposition throughout the history of the CVZ has not been constant, rather reflecting pulses of major explosive eruptions resulting in closely clustered groups of tephra separated by periods of reduced activity, relative volcanic quiescence or non-tephra deposition. As more regular activity became prevalent in the Pliocene, it was accompanied by more silicic magma compositions. Rhyolitic volcanic glass shards are characterised by predominantly calc-alkaline and minor high-K enriched major element compositions. Major element compositional variability of the tephras deposited between 10 Ma and 2 Ma reveals magma batches with pre-eruptive compositional gradients implying a broad control by fractional crystallisation. Trace element characterisation of glass shards reveals the role of magmatic processes that are not readily apparent in the relatively homogeneous major element compositions. Multi-element diagrams show prominent negative Sr and Ti anomalies against primitive mantle likely caused by various degrees of plagioclase and titanomagnetite fractional crystallisation in shallow magma chambers. Relative Nb depletion, characteristic of arc volcanism, is moderate in CVZ tephras. HFSEs (e.g. Nb, Zr, Ti) and HREEs (e.g. Yb, Lu) remain immobile during slab fluid flux suggesting they are derived from the mantle wedge. LILE (e.g. Rb, Cs, Ba, Sr) and LREE (e.g. La, Ce) enrichments are consistent with slab fluid contribution. B/La and Li/Y ratios can be used as a proxy for the flux of subducting material to the mantle wedge, they suggest there is a strong influence from this component in the generation of CVZ arc magmas, potentially inducing melting. CVZ tephra show long-term coherent variability in trace element geochemistry. Post ~ 4 Ma tephras display a more consistent, less variable, chemical fingerprint that persists up to and across the CVZ/TVZ transition at ~ 2 Ma. Initiation of TVZ volcanism may have occurred earlier than is presently considered, or CVZ to TVZ volcanism may have occurred without significant changes in magma generation processes.</p>

scholarly journals Identification of a Kulshan caldera correlative tephra in the Palouse loess of Washington State, northwest USA

2016 ◽  
Vol 86 (2) ◽  
pp. 232-241 ◽  
Author(s):  
Georgina E. King ◽  
Nicholas J.G. Pearce ◽  
Helen M. Roberts ◽  
Victoria C. Smith ◽  
John A. Westgate ◽  
...  
Keyword(s):  
Trace Element ◽  
Pacific Northwest ◽  
Washington State ◽  
Fractional Crystallisation ◽  
Early Pleistocene ◽  
East Central ◽  
Trace Element Chemistry ◽  
The Pacific ◽  
Eruptive Volume ◽  
Reversed Polarity

AbstractThe Kulshan caldera formed at ∼1.15 Ma on the present-day site of Mt. Baker, Washington State, northwest USA and erupted a compositionally zoned (dacite-rhyolite) magma and a correlative eruptive, the Lake Tapps tephra. This tephra has previously been described, but only from the Puget Lowland of NW Washington. Here an occurrence of a Kulshan caldera correlative tephra is described from the Quaternary Palouse loess at the Washtucna site (WA-3). Site WA-3 is located in east-central Washington, ∼340 km southeast of the Kulshan caldera and ∼300 km east-southeast of the Lake Tapps occurrence in the Puget Lowland. Major- and trace element chemistry and location of the deposit at Washtucna within reversed polarity sediments indicates that it is not correlative with the Mesa Falls, Rockland, Bishop Ash, Lava Creek B or Huckleberry Ridge tephras. Instead the Washtucna deposit is related to the Lake Tapps tephra by fractional crystallisation, but is chemically distinct, a consequence of its eruption from a compositionally zoned magma chamber. The correlation of the Washtucna occurrence to the Kulshan caldera-forming eruption indicates that it had an eruptive volume exceeding 100 km3, and that its tephra could provide a valuable early-Pleistocene chronostratigraphic marker in the Pacific Northwest.

Confined PEO crystallisation in immiscible PEO/PLLA blends

RSC Advances ◽  
2016 ◽  
Vol 6 (37) ◽  
pp. 30937-30950 ◽  
Author(s):  
Thiago do Carmo Rufino ◽  
Maria Isabel Felisberti
Keyword(s):  
Crystalline Phase ◽  
Fractional Crystallisation

PEO/PLLA blends are immiscible. PEO phase is confined into PLLA interlamellar and interspherulitic regions and a confined and fractional crystallisation of PEO occurs as the density of the PLLA crystalline phase increases.

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