The primary neutral salt effect in the catalytic hydrolysis of ethyl acetate

1930 ◽  
Vol 26 ◽  
pp. 217 ◽  
Author(s):  
Robert A. Robinson
1913 ◽  
Vol 35 (4) ◽  
pp. 396-418 ◽  
Author(s):  
William E. Henderson ◽  
David R. Kellogg

1981 ◽  
Vol 46 (12) ◽  
pp. 3104-3109 ◽  
Author(s):  
Miroslav Ludwig ◽  
Oldřich Pytela ◽  
Miroslav Večeřa

Rate constants of non-catalyzed hydrolysis of 3-acetyl-1,3-diphenyltriazene (I) and 3-(N-methylcarbamoyl)-1,3-diphenyltriazene (II) have been measured in the presence of salts (ammonium chloride, potassium chloride, lithium chloride, sodium chloride and bromide, ammonium sulphate, potassium sulphate, lithium sulphate, sodium sulphate and zinc sulphate) within broad concentration ranges. Temperature dependence of the hydrolysis of the substrates studied has been measured in the presence of lithium sulphate within temperature range 20° to 55 °C. The results obtained have been interpreted by mechanisms of hydrolysis of the studied substances.


1986 ◽  
Vol 51 (12) ◽  
pp. 2781-2785 ◽  
Author(s):  
M. Martín Herrera ◽  
J. J. Maraver Puig ◽  
F. Sánchez Burgos

A study is made on the kinetic salt effect on the reaction of hydrolysis of several charged esters in alkaline media. The results are interpreted on the basis of the coulombic interaction, the salting in of hydroxide ion and a third component depending on size of the substrate.


1996 ◽  
Vol 27 (1-2) ◽  
pp. 167-173 ◽  
Author(s):  
Zhaoqi Zhan ◽  
Martin Müllner ◽  
Johannes A. Lercher

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