scholarly journals Contributions to the study of strong electrolytes. I. The elimination of potential due to liquid contact. II. The potentials of silver nitrate solutions

1907 ◽  
Vol 2 (February) ◽  
pp. 213 ◽  
Author(s):  
Alexander Charles Cumming
Keyword(s):  
Silver Nitrate ◽  
Strong Electrolytes ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions

scholarly journals CONDUCTANCES OF STRONG SOLUTIONS OF STRONG ELECTROLYTES

1950 ◽  
Vol 28b (2) ◽  
pp. 43-55 ◽  
Author(s):  
Alan N. Campbell ◽  
Elinor M. Kartzmark
Keyword(s):  
Silver Nitrate ◽  
Ammonium Nitrate ◽  
Nitrate Solution ◽  
Strong Solutions ◽  
Silver Nitrate Solution ◽  
Weak Electrolyte ◽  
Strong Electrolytes ◽  
Conductance Ratio ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions

The conductances, densities, and viscosities of solutions of silver nitrate and of ammonium nitrate, at 25 °C., have been determined at concentrations ranging from 0.1 N to saturation (about 9 and 11 N respectively). By way of comparison, the same data have been obtained for the weak electrolyte acetic acid, up to 99.7% by weight concentration. It is shown that the weak electrolyte, at these concentrations, deviates even more from the Ostwald dilution law than do the strong electrolytes. Various attempts have been made to correct the conductance for viscosity. In addition to the older methods, two new attempts have been made, viz.; sugar was added to N/10 silver nitrate (used as the basis for these calculations) until its viscosity became equal to each of the silver nitrate solutions in turn. The conductance of a N/10 silver nitrate solution containing enough sugar to make its viscosity exactly equal to that of any given silver nitrate solution was used in the evaluation of the conductance ratio. Again, the viscosities of silver nitrate solutions at different temperatures were determined and the conductance found at the temperature at which the viscosity had become equal to that of N/10 silver nitrate at 25 °C. This conductance was used as the numerator in the conductance ratio. All attempts, however, resulted in "overcorrection", that is, in an apparently increasing equivalent conductance, with increasing concentration, after a certain concentration is reached. It is shown that a remarkable agreement exists, in the case of ammonium nitrate, with the Walden modification of the Ostwald formula.

Induction period of the crystallization of silver nitrate solutions in ethylene glycol

1991 ◽  
Vol 56 (10) ◽  
pp. 2142-2147
Author(s):  
Ivo Sláma
Keyword(s):  
Ethylene Glycol ◽  
Silver Nitrate ◽  
Induction Period ◽  
Glass Forming Ability ◽  
Transformation Theory ◽  
Concentration Region ◽  
Glass Forming ◽  
Temperature Transformation ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions

The dependence of the induction period of crystallization on supercooling was examined for the silver nitrate-ethylene glycol system over the concentration region of silver nitrate lome fraction of 0 to 0.12. Addition of AgNO3 to ethylene glycol was found to increase considerably the critical induction period of crystallization, although to a lesser extent than Ca(NO3)2, CaCl2, ZnCl2, LiCl and LiNO3 do. The effect of these salts on the critical induction period of crystallization in dimethylsulfoxide, dimethylformamide, dimethylacetamide and methanol was compared in terms of the solvent-rich composition limit of the glass-forming ability. By using the TTT(Time-Temperature-Transformation) theory, it has been deduced that the effect of the salts on the critical induction period of crystallization of ethylene glycol is probably due to the different dependences of viscosity on their concentration in ethylene glyco in the supercooling region.

Formation of nanoscale supramolecular aggregates in cysteine-silver nitrate solutions

2008 ◽  
Vol 3 (11-12) ◽  
pp. 716-721 ◽  
Author(s):  
P. V. Komarov ◽  
I. P. Sannikov ◽  
S. D. Khizhnyak ◽  
M. M. Ovchinnikov ◽  
P. M. Pakhomov
Keyword(s):  
Silver Nitrate ◽  
Supramolecular Aggregates ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions

THE CONDUCTANCES OF STRONG SOLUTIONS OF STRONG ELECTROLYTES AT 95°

1952 ◽  
Vol 30 (2) ◽  
pp. 128-134 ◽  
Author(s):  
A. N. Campbell ◽  
E. M. Kartzmark
Keyword(s):  
Silver Nitrate ◽  
Ammonium Nitrate ◽  
Strong Solutions ◽  
Partial Molar Volumes ◽  
Concentrated Solutions ◽  
Temperature Coefficients ◽  
Equivalent Conductance ◽  
Strong Electrolytes ◽  
Made In ◽  
Nitrate Solutions

Measurements of conductance and fluidity of silver nitrate and of ammonium nitrate solutions, over a range of concentration varying from 0.05  N to 14  N (silver nitrate) and from 0.08  N to 15  N (ammonium nitrate) have been made. In both cases, a maximum is observed in the specific conductances but in neither case does a minimum occur in the plot of equivalent conductance against concentration. While the equivalent conductance in very dilute solutions is proportional to [Formula: see text], in very concentrated solutions it appears to be directly proportional to C. Temperature coefficients of conductance and of fluidity are evaluated and their theoretical importance discussed. Partial molar volumes of water in these solutions are evaluated.

Radiolytic and Photolytic Reduction of Aqueous Silver Nitrate Solutions

Nature ◽  
1964 ◽  
Vol 202 (4932) ◽  
pp. 590-591 ◽  
Author(s):  
H. A. MAHLMAN ◽  
T. E. WILLMARTH
Keyword(s):  
Silver Nitrate ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions

Thermochemical modification of Mg3Si2O5(OH)4 hydrosilicate nanotubes by silver nitrate solutions

2016 ◽  
Vol 42 (3) ◽  
pp. 288-294 ◽  
Author(s):  
T. P. Maslennikova ◽  
E. N. Korytkova ◽  
O. M. Kuznetsova ◽  
L. N. Pivovarova
Keyword(s):  
Silver Nitrate ◽  
Hydrosilicate Nanotubes ◽  
Thermochemical Modification ◽  
Silver Nitrate Solutions ◽  
Nitrate Solutions
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