EPR spectra and redox properties of radical cations of dibenzofuran, methylated dibenzofurans and bidibenzofurans: relation to the chemistry of dibenzofuran radical cation

1996 ◽  
pp. 1289 ◽  
Author(s):  
Lennart Eberson ◽  
Michael P. Hartshorn ◽  
Ola Persson ◽  
Finn Radner ◽  
Christopher J. Rhodes
Keyword(s):  
Radical Cation ◽  
Radical Cations ◽  
Redox Properties ◽  
Epr Spectra

Electron n-doping of a highly electron-deficient chlorinated benzodifurandione-based oligophenylene vinylene polymer using benzyl viologen radical cations

2021 ◽  
Author(s):  
Teck Lip Dexter Tam ◽  
Albertus Denny Handoko ◽  
Ting Ting Lin ◽  
Jianwei Xu
Keyword(s):  
Radical Cation ◽  
Radical Cations ◽  
Benzyl Viologen ◽  
Electron Doping ◽  
N Doping ◽  
Polyphenylene Vinylene

Successful electron-doping of highly electron-deficient chlorinated benzodifurandione-based polyphenylene vinylene using viologen radical cation.

Radical cation formation during the adsorption of polycyclic aromatic hydrocarbons on platinum oxide

1973 ◽  
Vol 26 (1) ◽  
pp. 221 ◽  
Author(s):  
JL Garnett ◽  
KJ Nicol ◽  
A Rainis
Keyword(s):  
Polycyclic Aromatic Hydrocarbons ◽  
Radical Cation ◽  
Aromatic Hydrocarbons ◽  
Hyperfine Splitting ◽  
Radical Cations ◽  
Platinum Oxide ◽  
Adsorbed Species ◽  
Experimental Conditions ◽  
Polycyclic Aromatic

Experimental conditions are reported for resolving the hyperfine splitting of e.p.r. spectra obtained from the interaction of polycyclic aromatic hydrocarbons with platinum oxide. By contrast with earlier interpretations where only a singlet was obtained even with perylene, the present results indicate that the adsorbed species are radical cations.

Radikalionen, 61 [1, 2]Dialkylamino-substituierte Acetylene und Allene:Ionisation, Oxidation und AlCl3-katalysierte Wasserstoffübertragung / Radical Ions, 61 [1, 2]Dialkylamino-substituted Acetylenes and Allenes:Ionisation, Oxidation and AlCl3-Catalyzed Hydrogen Transfer

1984 ◽  
Vol 39 (6) ◽  
pp. 763-770 ◽  
Author(s):  
Hans Bock ◽  
Wolfgang Kaim ◽  
Mitsuo Kira ◽  
Louis Réné ◽  
Heinz-Günther Viehe
Keyword(s):  
Radical Cation ◽  
Hydrogen Transfer ◽  
Radical Cations ◽  
Esr Spectra ◽  
Ionization Potentials ◽  
Radical Ions ◽  
Substituted Acetylenes

AbstractThe photoelectron (PE) spectra of bis(dialkylamino) acetylenes R2N-C≡C-NR2 and of tetrakis(dialkylamino) allenes (R2N)2C=C=C(NR2)2 with R = CH3, C2H5 exhibit characteristic ionization patterns which are assigned to π radical cation states of the two molecular halves twisted against each other. The low first ionization potentials between 7.0 eV and 7.7 eV stimu­lated attempts to oxidize using AlCl3 in H2CCl2 or D2CCl2. The hyperfine structured ESR spectra observed can be unequivocally assigned to the ethylene radical cations R2N-HC=CH -NR2˙⊕ which are formed from the obviously non-persistent species R2N-C≡C-NR2˙⊕ via a hydrogen transfer. During the oxidation of the dialkylamino-substituted allenes no paramagnetic intermedi­ates could be detected, presumably due to a rapid dimerisation of the allene radical cation (R2N)2C=C=C(NR2)2˙⊕.

EPR spectra and structure of bis-chlorinated dimethyl ether radical cation, CH2ClOCH2Cl+

2002 ◽  
Vol 4 (12) ◽  
pp. 2530-2533 ◽  
Author(s):  
Yoshiteru Itagaki ◽  
Peng Wang ◽  
Masaru Shiotani ◽  
Akinori Hasegawa
Keyword(s):  
Radical Cation ◽  
Dimethyl Ether ◽  
Epr Spectra

EPR spectra and structure of the radical cations of fluorinated benzenes

1997 ◽  
pp. 1625-1632 ◽  
Author(s):  
Akinori Hasegawa ◽  
Yoshiteru Itagaki ◽  
Masaru Shiotani
Keyword(s):  
Radical Cations ◽  
Epr Spectra
Sign in / Sign up

Export Citation Format

Share Document