Phosphonium ions of 2,4,6,8-tetra-tert-butyl-1,3,5,7-tetraphosphacubane and 1,2,5,6-tetraphosphatricyclo[4.2.0.02,5]-octa-3,7-diene in the gas phase: host–guest complexes, phosphonium ion decomposition pathways and interaction with onium ions (and carbocations). A field desorption (FD), fast atom bombardment (FAB) and tandem mass spectrometry (CAD–MS/MS) study

1995 ◽  
pp. 1191-1195 ◽  
Author(s):  
Kenneth K. Laali ◽  
Chrys Wesdemiotis ◽  
Michael Polce ◽  
Sărka Beranová
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Gas Phase ◽  
Fast Atom Bombardment ◽  
Tandem Mass ◽  
Field Desorption ◽  
Tert Butyl

Gas-Phase Reactivity of Glycosides and Methyl Glycosides with Cu+, Ag+ and Pb2+ Ions by Fast-Atom Bombardment and Tandem Mass Spectrometry

2001 ◽  
Vol 7 (4-5) ◽  
pp. 321-330 ◽  
Author(s):  
Jean-Yves Salpin ◽  
Laurence Boutreau ◽  
Violette Haldys ◽  
Jeanine Tortajada
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Gas Phase ◽  
Fast Atom Bombardment ◽  
The Other ◽  
Tandem Mass ◽  
Pyranose Ring ◽  
Analytical Potential ◽  
Anomeric Center

The analytical potential of the complexation of three isomeric monosaccharides (D-glucose, D-galactose, D-fructose)and two methyl glycosides ( O-methyl-α-D-glucose and O-methyl-β-D-glucose)by three metal ions, Ag+, Cu+ and Pb2+, has been investigated by fast-atom bombardment (FAB)ionization and tandem mass spectrometry. Our results have shown that the unimolecular reactivity of Ag+ complexes allows the characterization of the C(4)stereochemistry of the pyranose ring, whereas a distinction between D-glucose and D-fructose is not achieved. On the other hand, each of the three [Cu + monosaccharide]+ complexes exhibits specific dissociation patterns. We have also observed that Pb2+ ions induce the richest reactivity and are of particular interest for the identification of the three isomers. Finally, this study has demonstrated that the stereochemistry of the anomeric center of O-methyl-D-glucose is easily determined by reaction with Ag+ or Pb2+ ions. Several mechanisms are proposed to account for the main fragmentations of cationized glucose.

Coaxial continuous flow fast atom bombardment in conjunction with tandem mass spectrometry for the analysis of biomolecules

1989 ◽  
Vol 61 (22) ◽  
pp. 2504-2511 ◽  
Author(s):  
Leesa J. Deterding ◽  
M. Arthur. Moseley ◽  
Kenneth B. Tomer ◽  
James W. Jorgenson
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Continuous Flow ◽  
Fast Atom Bombardment ◽  
Tandem Mass

scholarly journals Fast atom bombardment mass spectra of the .BETA.-blocker nipradilol with nitrate ester group-tandem mass spectrometry (MS/MS) and B/E constant linked scanning.

1990 ◽  
Vol 38 (12) ◽  
pp. 3389-3394 ◽  
Author(s):  
Michiaki YONEDA ◽  
Kazuo TSUJIMOTO ◽  
Mamoru OHASHI ◽  
Masami SHIRATSUCHI ◽  
Yasushi OHKAWA ◽  
...  
Keyword(s):  
Mass Spectrometry ◽  
Tandem Mass Spectrometry ◽  
Beta Blocker ◽  
Mass Spectra ◽  
Fast Atom Bombardment ◽  
Ester Group ◽  
Tandem Mass ◽  
Nitrate Ester
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