Synthesis of 1-substituted indoles by the vapour phase reaction of N-substituted anilines with glycols and epoxides over a solid catalyst and a vapour phase dealkylation of 1-alkylindole

Author(s):  
Takuo Nishida ◽  
Yoshikazu Tokuda ◽  
Michihiro Tsuchiya
1995 ◽  
Vol 5 (11) ◽  
pp. 1953 ◽  
Author(s):  
Xinyong Li ◽  
Enhui Lin ◽  
Changyan Zhang ◽  
Shuben Li

2005 ◽  
Vol 107-108 ◽  
pp. 444-450 ◽  
Author(s):  
Susana Larrondo ◽  
Gonzalo Alvaro ◽  
Beatriz Irigoyen ◽  
Norma Amadeo

2006 ◽  
Vol 255 (1-2) ◽  
pp. 220-229 ◽  
Author(s):  
S. Sudha ◽  
M. Palanichamy ◽  
V.V. Balasubramanian ◽  
Banumathi Arabindoo ◽  
V. Murugesan

Water ◽  
2020 ◽  
Vol 12 (12) ◽  
pp. 3448
Author(s):  
Cristian Ferreiro ◽  
Natalia Villota ◽  
José Ignacio Lombraña ◽  
María J. Rivero

This work aims to study the sustainable catalytic ozonation of aniline promoted by granular active carbon (GAC) doped with TiO2. Aniline was selected as a model compound for the accelerator manufacturing industries used in the manufacture of rubber due to its environmental impact, low biodegradability, and harmful genotoxic effects on human health. Based on the evolution of total organic carbon (TOC), aniline concentration measured using high performance liquid chromatography (HPLC), pH and ozone concentration in liquid and gas phase, and catalyst loading, a three-phase reaction system has been modelled. The proposed three-phase model related the ozone transfer parameters and the pseudo-first order kinetic constants through three coefficients that involve the adsorption process, oxidation in the liquid, and the solid catalyst. The interpretation of the kinetic constants of the process allowed the predominance of the mechanism of Langmuir–Hinshelwood or modified Eley–Rideal to be elucidated. Seven intermediate aromatic reaction products, representative of the direct action of ozone and the radical pathway, were identified and quantified, as well as precursors of the appearance of turbidity, with which two possible routes of degradation of aniline being proposed.


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