Kinetic and structural EPR studies of radical polymerization. Monomer, dimer, trimer and mid-chain radicals formed via the initiation of polymerization of acrylic acid and related compounds with electrophilic radicals (˙OH, SO4–˙ and Cl2–˙)

1994 ◽  
pp. 1759-1769 ◽  
Author(s):  
Bruce C. Gilbert ◽  
John R. Lindsay Smith ◽  
Elizabeth C. Milne ◽  
Adrian C. Whitwood ◽  
Philip Taylor
Keyword(s):  
Acrylic Acid ◽  
Radical Polymerization ◽  
Related Compounds ◽  
Initiation Of Polymerization

Preparation of a phosphorous-free terpolymer as a decalcifying agent for removing calcium from crude oil

RSC Advances ◽  
2016 ◽  
Vol 6 (63) ◽  
pp. 58426-58433 ◽  
Author(s):  
Shuaishuai Ma ◽  
Zhilan Cai ◽  
Yuming Zhou ◽  
Shiwei Li ◽  
Shuang Liang
Keyword(s):  
Free Radical ◽  
Acrylic Acid ◽  
Crude Oil ◽  
Radical Polymerization ◽  
Free Radical Polymerization ◽  
Polymerization Reaction

A novel phosphorous-free terpolymer, used as a decalcifying agent for removing calcium from crude oil, was prepared through a free-radical polymerization reaction of acrylic acid, allylpolyethoxy amino carboxylate, and 2-hydroxyethyl acrylate.

Investigation on pH-switchable (itaconic acid/ethylene glycol/acrylic acid) based polymeric biocompatible hydrogel

RSC Advances ◽  
2016 ◽  
Vol 6 (108) ◽  
pp. 106821-106831 ◽  
Author(s):  
M. Sakthivel ◽  
D. S. Franklin ◽  
S. Sudarsan ◽  
G. Chitra ◽  
S. Guhanathan
Keyword(s):  
Free Radical ◽  
Acrylic Acid ◽  
Ethylene Glycol ◽  
Radical Polymerization ◽  
Itaconic Acid ◽  
Free Radical Polymerization ◽  
Ph Sensitive ◽  
Water Medium ◽  
New Variety ◽  
Polymeric Hydrogels

A new variety of pH-sensitive polymeric hydrogels (IAE) have been developed and evaluated as biocompatible hydrogels using synergetic combinations of itaconic acid (IA), acrylic acid (AA), and ethylene glycol (EG) in water medium by free radical polymerization.

scholarly journals Free-Radical Polymerization of Acrylic Acid under Extreme Reaction Conditions Mimicking Deep-Sea Hydrothermal Vents

ACS Omega ◽  
2017 ◽  
Vol 2 (6) ◽  
pp. 2765-2769 ◽  
Author(s):  
Keigo Kinoshita ◽  
Yoshinori Takano ◽  
Naohiko Ohkouchi ◽  
Shigeru Deguchi
Keyword(s):  
Free Radical ◽  
Acrylic Acid ◽  
Radical Polymerization ◽  
Deep Sea ◽  
Hydrothermal Vents ◽  
Free Radical Polymerization ◽  
Reaction Conditions
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