Enolization in radical cations of o-methylacetophenone and related species under cryogenic conditions

Author(s):  
Andrzej Marcinek ◽  
Jacek Michalak ◽  
Jacek Rogowski ◽  
Weilin Tang ◽  
Thomas Bally ◽  
...  
ChemInform ◽  
2010 ◽  
Vol 23 (48) ◽  
pp. no-no
Author(s):  
A. MARCINEK ◽  
J. MICHALAK ◽  
J. ROGOWSKI ◽  
W. TANG ◽  
T. BALLY ◽  
...  

1992 ◽  
Vol 86 (1) ◽  
pp. 168-172 ◽  
Author(s):  
Faustino Menegus ◽  
Liliana Cattaruzza ◽  
Leonardo Scaglioni ◽  
Enzio Ragg

1904 ◽  
Vol 58 (1493supp) ◽  
pp. 23927-23928
Author(s):  
Charles H. Stevenson
Keyword(s):  

2020 ◽  
Author(s):  
Oisin Shiels ◽  
P. D. Kelly ◽  
Cameron C. Bright ◽  
Berwyck L. J. Poad ◽  
Stephen Blanksby ◽  
...  

<div> <div> <div> <p>A key step in gas-phase polycyclic aromatic hydrocarbon (PAH) formation involves the addition of acetylene (or other alkyne) to σ-type aromatic radicals, with successive additions yielding more complex PAHs. A similar process can happen for N- containing aromatics. In cold diffuse environments, such as the interstellar medium, rates of radical addition may be enhanced when the σ-type radical is charged. This paper investigates the gas-phase ion-molecule reactions of acetylene with nine aromatic distonic σ-type radical cations derived from pyridinium (Pyr), anilinium (Anl) and benzonitrilium (Bzn) ions. Three isomers are studied in each case (radical sites at the ortho, meta and para positions). Using a room temperature ion trap, second-order rate coefficients, product branching ratios and reaction efficiencies are reported. </p> </div> </div> </div>


2012 ◽  
Vol 46 ◽  
pp. 298-305 ◽  
Author(s):  
A. D. Potemkin ◽  
T. Ahti

Riccia marginata Lindb. was described by S. O. Lindberg (1877) from the outskirts of the town of Sortavala near the north shore of Lake Ladoga, Republic of Karelia, Russia. The species has been forgotten in most recent liverwort accounts of Europe, including Russia. Lectotypification of R. marginata is provided. R. marginata shares most characters with R. beyrichiana Hampe ex Lehm. It differs from “typical” plants of R. beyrichiana in having smaller spores, with ± distinctly finely areolate to roughly papillose proximal surfaces and a narrower and shorter thallus, as well as in scarcity or absence of marginal hairs. It may represent continental populations of the suboceanic-submediterranean R. beyrichiana, known in Russia from the Leningrad Region and Karelia only. The variability of spore surfaces in R. beyrichiana is discussed and illustrated by SEM images. A comparison with the spores of R. bifurca Hoffm. is provided. The question how distinct R. marginata is from R. beyrichiana needs to be clarified by molecular studies in the future, when adequate material is available. R. marginata is for the time being, provisionally, included in R. beyrichiana.


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