Molecular recognition by modified cyclodextrins. Inclusion complexation of β-cyclodextrin 6-O-monobenzoate with acyclic and cyclic hydrocarbons

Author(s):  
Lin-Hui Tong ◽  
Zhi-Jie Hou ◽  
Yoshihisa Inoue ◽  
Akira Tai
Author(s):  
Narayanasamy Rajendiran ◽  
J. Thulasidhasan ◽  
M. Jude Jenita

The inclusion complexation of 2-aminobenzoic acid (2ABA), 3-aminobenzoic acid (3ABA), and 4-aminobenzoic acid (4ABA) with α-cyclodextrin (α-CD), β-cyclodextrin (β-CD), hydroxypropyl-α-cyclodextrin (HP-α-CD) and hydroxypropyl-β-cyclodextrin (HP-β-CD) were studied in buffer solutions of differentpHs (pH~1 andpH~7) and it was carried out using UV-Visible, steady-state and time-resolved fluorescence. Dual fluorescence was observed for all the compounds in aqueous and CD medium. All the ABAs forms 1:1 inclusion complex at pH ~ 1 solution and mixture of 1:1 and 1:2 inclusion complex at pH ~7. With CDs, dual luminescence appeared at pH ~ 1 indicates, both NH3+and COOH groups are present in the interior of the CDs cavities. FT-IR,1H NMR, results suggest ABAs formed a stable inclusion complex with the CDs.


1991 ◽  
Vol 54 (4) ◽  
pp. 593-597 ◽  
Author(s):  
Shingo Minato ◽  
Tetsuo Osa ◽  
Masahiko Morita ◽  
Asao Nakamura ◽  
Hiroshi Ikeda ◽  
...  

2007 ◽  
Vol 37 (2) ◽  
pp. 249-264 ◽  
Author(s):  
Mahmoud M. Al Omari ◽  
Musa I. El-Barghouthi ◽  
Mohammad B. Zughul ◽  
J. Eric D. Davies ◽  
Adnan A. Badwan

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