Combined X-ray crystallographic and infrared and Raman spectroscopic study of hydrogen bonding patterns in keto acid phosphoranes

Author(s):  
Andrew D. Abell ◽  
John O. Trent ◽  
Kathryn B. Morris
2021 ◽  
Vol 22 (10) ◽  
pp. 5380
Author(s):  
Boris A. Kolesov

The work outlines general ideas on how the frequency and the intensity of proton vibrations of X–H×××Y hydrogen bonding are formed as the bond evolves from weak to maximally strong bonding. For this purpose, the Raman spectra of different chemical compounds with moderate, strong, and extremely strong hydrogen bonds were obtained in the temperature region of 5 K–300 K. The dependence of the proton vibrational frequency is schematically presented as a function of the rigidity of O-H×××O bonding. The problems of proton dynamics on tautomeric O–H···O bonds are considered. A brief description of the N–H···O and C–H···Y hydrogen bonds is given.


2021 ◽  
Vol 33 (3) ◽  
pp. 283-297
Author(s):  
Evgeniy Nikolaevich Kozlov ◽  
Ekaterina Nikolaevna Fomina ◽  
Vladimir Nikolaevich Bocharov ◽  
Mikhail Yurievich Sidorov ◽  
Natalia Sergeevna Vlasenko ◽  
...  

Abstract. Raman spectra of three natural carbonophosphates (sidorenkite, bonshtedtite, and bradleyite) with the general formula Na3MCO3PO4 (M is Mn, Fe, and Mg) were studied and compared. These spectra showed from 21 to 24 vibrational bands, of which the two most intense (964±5 and 1074±3 cm−1) correspond to the υ1(P–O) and υ1(C–O) modes. These two bands split into doublet peaks due to the occurrence of isomorphic impurities. It was found that the crystallographic orientation of the sample influences the intensity of most bands. Most bands assigned to the same vibrations showed a regular shift (the smallest in sidorenkite spectra, an intermediate in bonshtedtite, and the largest in bradleyite). We propose an algorithm that allows for diagnostics of carbonophosphates in inclusions by their Raman spectra, providing a reliable result even in the absence of energy-dispersive X-ray spectroscopy (EDX) data.


2016 ◽  
Vol 178 ◽  
pp. 41-61 ◽  
Author(s):  
Benjamin J.A. Moulton ◽  
Grant S. Henderson ◽  
Hiroshi Fukui ◽  
Nozomu Hiraoka ◽  
Dominique de Ligny ◽  
...  

ChemInform ◽  
2010 ◽  
Vol 24 (23) ◽  
pp. no-no
Author(s):  
J. MOCHINAGA ◽  
M. IKEDA ◽  
K. IGARASHI ◽  
K. FUKUSHIMA ◽  
Y. IWADATE

2002 ◽  
Vol 121 (5) ◽  
pp. 275-279 ◽  
Author(s):  
Zhongwu Wang ◽  
V Pischedda ◽  
S.K Saxena ◽  
Peter Lazor

Sign in / Sign up

Export Citation Format

Share Document