Kinetics and mechanism of the Lewis acid-catalysed addition of alcohols to ketenes in diethyl ether solution

1985 ◽  
pp. 1551 ◽  
Author(s):  
Nai L. Poon ◽  
Derek P. N. Satchell
Keyword(s):  
Lewis Acid ◽  
Diethyl Ether ◽  
Kinetics And Mechanism ◽  
Ether Solution

Behavior of Triphenylethylene Dianion in Diethyl Ether Solution

1992 ◽  
Vol 21 (7) ◽  
pp. 1149-1152 ◽  
Author(s):  
Yukihiro Yokoyama ◽  
Osamu Kikuchi
Keyword(s):  
Diethyl Ether ◽  
Ether Solution

Notizen: Identification of a Baker-type Mechanism in Additions to p-Nitrophenyl Isothiocyanate in Diethyl Ether Solution

1989 ◽  
Vol 44 (10) ◽  
pp. 1329-1330
Author(s):  
Derek P. N. Satchell ◽  
Rosemary S. Satchell
Keyword(s):  
Diethyl Ether ◽  
Ether Solution ◽  
Prototropic Rearrangement

Kinetic evidence is presented which strongly suggests that in the diethyl ether solution the aminolysis of p-nitrophenyl isothiocyanate proceeds via a mechanism involving a 1:1-addition intermediate which undergoes catalyzed prototropic rearrangement to the product (Baker-type mechanism).

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