Temperature dependence of activation parameters in the neutral ester hydrolysis in t-butyl alcohol–water solutions

1983 ◽  
pp. 1573-1576 ◽  
Author(s):  
Liisa T. Kanerva
Keyword(s):  
Temperature Dependence ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Ester Hydrolysis ◽  
Water Solutions ◽  
Alcohol Water

scholarly journals Temperature Dependence of Activation Parameters in the Neutral Ester Hydrolysis in Methanol--Water Solutions.

1983 ◽  
Vol 37b ◽  
pp. 755-760 ◽  
Author(s):  
Liisa T. Kanerva ◽  
Einar Uggerud ◽  
Kristin Brobakke ◽  
Georg E. Carlberg ◽  
Olov Sterner ◽  
...  
Keyword(s):  
Temperature Dependence ◽  
Activation Parameters ◽  
Ester Hydrolysis ◽  
Water Solutions

scholarly journals Temperature Dependence of Activation Parameters in the Neutral Ester Hydrolysis in Acetone+Water Solutions.

1984 ◽  
Vol 38b ◽  
pp. 803-807 ◽  
Author(s):  
Liisa T. Kanerva ◽  
Erkki K. Euranto ◽  
Nils J. Cleve ◽  
Lars Mörch ◽  
Torbjörn Norin
Keyword(s):  
Temperature Dependence ◽  
Activation Parameters ◽  
Ester Hydrolysis ◽  
Water Solutions ◽  
Acetone Water

Pressure effect on water dynamics in tert-butyl alcohol/water solutions

2006 ◽  
Vol 18 (36) ◽  
pp. S2363-S2371 ◽  
Author(s):  
Vania Calandrini ◽  
Antonio Deriu ◽  
Giuseppe Onori ◽  
Alessandro Paciaroni ◽  
Mark T F Telling
Keyword(s):  
Pressure Effect ◽  
Butyl Alcohol ◽  
Water Dynamics ◽  
Water Solutions ◽  
Tert Butyl ◽  
Tert Butyl Alcohol ◽  
Alcohol Water

Kinetics of oxidation of the bis(ethylenediamine)mercaptoacetatocobalt(III) and cysteinato-bis(ethylenediamine)cobalt(III) ions by hydrogen peroxide in mixed aqueous-nonaqueous solutions

1988 ◽  
Vol 53 (3) ◽  
pp. 554-562
Author(s):  
Ján Benko ◽  
Oľga Vollárová ◽  
Miroslav Kovarčík
Keyword(s):  
Hydrogen Peroxide ◽  
Reaction Rate ◽  
Activation Parameters ◽  
Butyl Alcohol ◽  
Acid Base ◽  
Kinetics Of Oxidation ◽  
Tert Butyl Alcohol ◽  
Alcohol Water ◽  
Acid Base Equilibrium ◽  
Kinetics Of

The kinetics of oxidation of the coordinatively bonded sulphur in the cysteinato-bis(ethylenediamine)cobalt(III) and bis(ethylenediamine)mercaptoacetatocobalt(III) complexes by hydrogen peroxide to the sulphoxides was examined in HClO4 solutions (c(HClO4) = 1 – 500 mmol l-1) with a view to obtaining data characterizing the effect of the acid-base equilibria of the reactants on the reaction rate. The reaction rate was found affected particularly by the acid-base equilibrium of the oxidant, which plays a role in strongly acid solutions. The oxidation was also studied in water-methyl alcohol, water-tert-butyl alcohol and water-ethylene glycol mixtures, and the effect of the mole fraction of the nonaqueous component on the rate constant and thermodynamic activation parameters was examined.

Sign in / Sign up

Export Citation Format

Share Document