A comparison of the mechanisms of hydrolysis of diphenylketene and dimethylketene in diethyl ether solution

1983 ◽  
pp. 1381 ◽  
Author(s):  
Nai L. Poon ◽  
Derek P. N. Satchell
Keyword(s):  
Diethyl Ether ◽  
Ether Solution ◽  
Hydrolysis Of

Behavior of Triphenylethylene Dianion in Diethyl Ether Solution

1992 ◽  
Vol 21 (7) ◽  
pp. 1149-1152 ◽  
Author(s):  
Yukihiro Yokoyama ◽  
Osamu Kikuchi
Keyword(s):  
Diethyl Ether ◽  
Ether Solution

Notizen: Identification of a Baker-type Mechanism in Additions to p-Nitrophenyl Isothiocyanate in Diethyl Ether Solution

1989 ◽  
Vol 44 (10) ◽  
pp. 1329-1330
Author(s):  
Derek P. N. Satchell ◽  
Rosemary S. Satchell
Keyword(s):  
Diethyl Ether ◽  
Ether Solution ◽  
Prototropic Rearrangement

Kinetic evidence is presented which strongly suggests that in the diethyl ether solution the aminolysis of p-nitrophenyl isothiocyanate proceeds via a mechanism involving a 1:1-addition intermediate which undergoes catalyzed prototropic rearrangement to the product (Baker-type mechanism).

Kinetics of individual steps in reaction network ethanol-diethyl ether-ethylene-water on alumina

1986 ◽  
Vol 51 (4) ◽  
pp. 763-773 ◽  
Author(s):  
Vladimír Morávek ◽  
Miloš Kraus
Keyword(s):  
Diethyl Ether ◽  
Reaction Network ◽  
Reaction Rates ◽  
Rate Equations ◽  
Initial Reaction ◽  
Ethanol Dehydration ◽  
Partial Pressures ◽  
Type Rate ◽  
Kinetics Of ◽  
Hydrolysis Of

The rates of single reactions have been measured at 250 °C in the complex reaction of ethanol dehydration to ethylene and to diethyl ether involving also hydrolysis of the ether, its disproportionation to ethanol and ethylene and its dehydration to ethylene. The found dependences of the initial reaction rates on partial pressures of the reactants were correlated by semiempirical Langmuir-Hinshelwood type rate equations.

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