N-hydroxy-compounds as acyl transfer agents. Part 2. Kinetics and mechanism of hydrolysis and aminolysis of 1-hydroxypyrazole and 1-hydroxyimidazole esters

1977 ◽  
pp. 231 ◽  
Author(s):  
Daniel G. McCarthy ◽  
Anthony F. Hegarty
Keyword(s):  
Kinetics And Mechanism ◽  
Acyl Transfer ◽  
Mechanism Of Hydrolysis ◽  
Hydroxy Compounds ◽  
Transfer Agents

The Kinetics and Mechanism of Hydrolysis of Tetrachloroaurate(III)

1966 ◽  
Vol 5 (11) ◽  
pp. 1943-1946 ◽  
Author(s):  
Franklin H. Fry ◽  
Gordon A. Hamilton ◽  
John Turkevich
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of Hydrolysis ◽  
Hydrolysis Of

scholarly journals Kinetics and Mechanism of Hydrolysis of Acetylthiocholine by Butyrylcholine Esterase

2002 ◽  
Vol 57 (11-12) ◽  
pp. 1072-1077 ◽  
Author(s):  
Karel Komers ◽  
Alexandr Čegan ◽  
Marek Link
Keyword(s):  
Acetic Acid ◽  
Kinetics And Mechanism ◽  
Kinetics Parameters ◽  
Mechanism Of Hydrolysis ◽  
Ph Stat ◽  
Stat Method ◽  
Ellman’S Method ◽  
Hydrolysis Of

Kinetics and mechanism of hydrolysis of acetylthiocholine by the enzyme butyrylcholine esterase was studied. The spectrophotometric Ellman’s method and potentiometric pH-stat method were used for continuous determination of the actual concentration of the products thiocholine and acetic acid in the reaction mixture. The validity of the Michaelis-Menten (Briggs-Haldane) equation in the whole course of the reaction under used conditions was proved. The corresponding kinetics parameters (Vm and KM) were calculated from the obtained dependences of concentration of thiocholine or acetic acid vs. time and compared. From this comparison the deciding kinetic role of the step producing thiocholine was derived. The values of initial molar concentration of the enzyme and of the rate constants of the kinetic model were estimated.

ChemInform Abstract: KINETICS AND MECHANISM OF HYDROLYSIS OF CHLORO-1,3,5-TRIAZINES. ATRAZINE

1982 ◽  
Vol 13 (4) ◽  
Author(s):  
S. J. PLUST ◽  
J. R. LOEHE ◽  
F. J. FEHER ◽  
J. H. BENEDICT ◽  
H. F. HERBRANDSON
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of Hydrolysis ◽  
Hydrolysis Of

Kinetics and mechanism of hydrolysis of 4-phenylallophanates

1984 ◽  
pp. 1233 ◽  
Author(s):  
Mohamed Mowafak Al Sabbagh ◽  
Michelle Calmon ◽  
Jean-Pierre Calmon
Keyword(s):  
Kinetics And Mechanism ◽  
Mechanism Of Hydrolysis ◽  
Hydrolysis Of
Sign in / Sign up

Export Citation Format

Share Document