Vinyl carbanions. Part I. Kinetics of hydrogen–deuterium exchange in fluoren-9-ylideneacetonitrile catalysed by sodium ethoxide

1976 ◽  
pp. 253-256 ◽  
Author(s):  
B. A. Feit ◽  
L. Bohor ◽  
S. Rubinraut
Keyword(s):  
Sodium Ethoxide ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Hydrogen Deuterium ◽  
Kinetics Of

Base-catalyzed Deuteration of Tricarbonylchromium Complexes

1972 ◽  
Vol 50 (1) ◽  
pp. 118-121 ◽  
Author(s):  
M. Ashraf
Keyword(s):  
Sodium Ethoxide ◽  
Deuterium Exchange ◽  
Steric Effects ◽  
Hydrogen Deuterium Exchange ◽  
Kinetically Controlled ◽  
Hydrogen Deuterium ◽  
Random Substitution ◽  
Tricarbonylchromium Complexes

Hydrogen–deuterium exchange in tricarbonylchromium complexes of anisole, ethylbenzoate, and N,N-dimethylaniline has been studied for solutions in ethanol-O-d1, containing sodium ethoxide. The extent of deuteration has been estimated mass spectroscopically and the position of deuteration by n.m.r. spectroscopy. In this kinetically controlled reaction ortho-substitution has been found to be predominantly preferred in case of anisole complex, whereas random substitution was observed (n.m.r.) for ethylbenzoate complex. The results are interpreted in terms of chelative, inductive, mesomeric, and steric effects of the substituents.

Kinetics of Hydrogen–Deuterium Exchange Reactions of Methane and Deuterated Acid FAU- and MFI-Type Zeolites

1999 ◽  
Vol 183 (2) ◽  
pp. 355-367 ◽  
Author(s):  
Bart Schoofs ◽  
Johan A. Martens ◽  
Pierre A. Jacobs ◽  
Robert A. Schoonheydt
Keyword(s):  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Exchange Reactions ◽  
Hydrogen Deuterium ◽  
Kinetics Of

Kinetics of hydrogen-deuterium exchange in ATPase from a thermophilic bacterium PS3

1978 ◽  
Vol 80 (4) ◽  
pp. 929-935 ◽  
Author(s):  
Shigeo Ohta ◽  
Mamoru Nakanishi ◽  
Masamichi Tsuboi ◽  
Masasuke Yoshida ◽  
Yasuo Kagawa
Keyword(s):  
Thermophilic Bacterium ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Hydrogen Deuterium ◽  
Kinetics Of

scholarly journals Hydrogen/Deuterium Exchange Kinetics of Apolipophorin-III in Lipid-free and Phospholipid-bound States

1996 ◽  
Vol 271 (38) ◽  
pp. 23089-23095 ◽  
Author(s):  
Vincent Raussens ◽  
Vasanthy Narayanaswami ◽  
Erik Goormaghtigh ◽  
Robert O. Ryan ◽  
Jean-Marie Ruysschaert
Keyword(s):  
Bound States ◽  
Deuterium Exchange ◽  
Hydrogen Deuterium Exchange ◽  
Apolipophorin Iii ◽  
Hydrogen Deuterium ◽  
Exchange Kinetics ◽  
Kinetics Of
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