Free-radical reductions of arenediazonium ions in aqueous solution. Part III. Kinetics of reactions of toluene-p-diazonium ions with ethanol, propan-2-ol, and acetaldehyde

1975 ◽  
pp. 751 ◽  
Author(s):  
John E. Packer ◽  
Russell K. Richardson
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Diazonium Ions ◽  
Kinetics Of

Free-radical reductions of arenediazonium ions in aqueous solution. IV. Kinetics of reactions of para-substituted diazonium ions with benzyl alcohol, isopropyl alcohol and methanol

1980 ◽  
Vol 33 (5) ◽  
pp. 965 ◽  
Author(s):  
JE Packer ◽  
CJ Heighway ◽  
HM Miller ◽  
BC Dobson
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Benzyl Alcohol ◽  
Rate Constants ◽  
Isopropyl Alcohol ◽  
Diazo Compounds ◽  
Reaction Step ◽  
Diazonium Ions ◽  
Kinetics Of ◽  
Slow Propagation

Electron-withdrawing substituents are shown to increase the chain length of free-radical hydro-dediazoniation reactions, but the actual reaction step causing the substituent effect depends on the relative rates of propagation and termination reactions. With benzyl alcohol as reducing agent the rate of the slow propagation step is increased, while with isopropyl alcohol the rate of the termination step is decreased. Rate constants for some reactions of radicals with diazonium ions are reported, and the nature of some of these reactions and their implication for an understanding of the homolysis of aromatic diazo compounds are discussed.

Free-Radical Propagation Kinetics of N -Vinyl Formamide in Aqueous Solution Studied by PLP-SEC

2010 ◽  
Vol 211 (5) ◽  
pp. 580-593 ◽  
Author(s):  
Marek Stach ◽  
Igor Lacík ◽  
Peter Kasák ◽  
Dušan Chorvát ◽  
Alan J. Saunders ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Kinetics Of ◽  
Radical Propagation

Termination Kinetics of the Free-Radical Polymerization of Nonionized Methacrylic Acid in Aqueous Solution

2008 ◽  
Vol 41 (10) ◽  
pp. 3513-3520 ◽  
Author(s):  
Sabine Beuermann ◽  
Michael Buback ◽  
Pascal Hesse ◽  
Robin A. Hutchinson ◽  
Silvia Kukučková ◽  
...  
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Radical Polymerization ◽  
Methacrylic Acid ◽  
Free Radical Polymerization ◽  
Kinetics Of

Comparing the performances of various density functionals for modelling the mechanisms and kinetics of bimolecular free radical reactions in aqueous solution

2019 ◽  
Vol 21 (42) ◽  
pp. 23425-23440
Author(s):  
Ivana Nikšić-Franjić ◽  
Ivan Ljubić
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Radical Reactions ◽  
Organic Substrates ◽  
Density Functionals ◽  
Free Radical Reactions ◽  
Kinetics Of

We systematically tested the performances of 18 density functionals for the mechanisms and kinetics of reactions of the α-hydroxyisopropyl radical with 9 organic substrates.

Mechanism and kinetics of free-radical degradation of xyloglucan in aqueous solution

Polymer ◽  
2010 ◽  
Vol 51 (26) ◽  
pp. 6115-6122 ◽  
Author(s):  
Amilcar Pillay Narrainen ◽  
Peter A. Lovell
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Radical Degradation ◽  
Mechanism And Kinetics ◽  
Kinetics Of

Propagation Kinetics of Free-Radical Methacrylic Acid Polymerization in Aqueous Solution. The Effect of Concentration and Degree of Ionization

2007 ◽  
Vol 248 (1) ◽  
pp. 23-32 ◽  
Author(s):  
Sabine Beuermann ◽  
Michael Buback ◽  
Pascal Hesse ◽  
Silvia Kukučková ◽  
Igor Lacık
Keyword(s):  
Aqueous Solution ◽  
Free Radical ◽  
Methacrylic Acid ◽  
Degree Of Ionization ◽  
Kinetics Of
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