Kinetics and mechanism of the carboxylic acid catalysed ethanolysis of p-chlorophenyl isocyanate in diethyl ether

Author(s):  
Steven A. Lammiman ◽  
Rosemary S. Satchell
1999 ◽  
Vol 23 (3) ◽  
pp. 176-177
Author(s):  
Garima Goswami ◽  
Seema Kothari ◽  
Kalyan K. Banerji

The oxidation of aliphatic aldehydes by benzyltrimethylammonium tribromide involves the formation of an intermediate complex and its subsequent decomposition in the rate-determining step to the corresponding carboxylic acid.


1999 ◽  
Vol 23 (5) ◽  
pp. 308-309
Author(s):  
Anupama Bohra ◽  
Pradeep K. Sharma ◽  
Kalyan K. Banerji

Oxidation of aliphatic aldehydes by benzyltrimethylammonium chlorobromate to the corresponding carboxylic acid proceeds via the transfer of a hydride ion from the aldehyde hydrate to the oxidant.


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