Electrochemical reactions. Part X. 4-Styrylpyridine: polarography and cyclic voltammetry in dimethylformamide and reduction in protic solvents

1972 ◽  
pp. 1663 ◽  
Author(s):  
Khaled Alwair ◽  
J. F. Archer ◽  
James Grimshaw
Keyword(s):  
Cyclic Voltammetry ◽  
Electrochemical Reactions ◽  
Protic Solvents

scholarly journals Multielectron, multisubstrate molecular catalysis of electrochemical reactions: Formal kinetic analysis in the total catalysis regime

2017 ◽  
Vol 114 (43) ◽  
pp. 11303-11308 ◽  
Author(s):  
Cyrille Costentin ◽  
Daniel G. Nocera ◽  
Casey N. Brodsky
Keyword(s):  
Cyclic Voltammetry ◽  
Small Molecule ◽  
Rate Constants ◽  
Electrochemical Reactions ◽  
Cyclic Voltammograms ◽  
Experimental Systems ◽  
Kinetic Information ◽  
Formal Kinetic ◽  
Molecular Catalysis

Cyclic voltammetry responses are derived for two-electron, two-step homogeneous electrocatalytic reactions in the total catalysis regime. The models developed provide a framework for extracting kinetic information from cyclic voltammograms (CVs) obtained in conditions under which the substrate or cosubstrate is consumed in a multielectron redox process, as is particularly prevalent for very active catalysts that promote energy conversion reactions. Such determination of rate constants in the total catalysis regime is a prerequisite for the rational benchmarking of molecular electrocatalysts that promote multielectron conversions of small-molecule reactants. The present analysis is illustrated with experimental systems encompassing various limiting behaviors.

scholarly journals Voltammetric investigations of anodic dissolution of natural mineral chalcopyrite

2008 ◽  
Vol 44 (1) ◽  
pp. 115-124 ◽  
Author(s):  
M. Vukovic ◽  
Z.D. Stankovic ◽  
M. Rajcic-Vujasinovic ◽  
V. Cvetkovski
Keyword(s):  
Cyclic Voltammetry ◽  
Sulfuric Acid ◽  
Kinetic Analysis ◽  
Electrochemical Behavior ◽  
Electrochemical Reactions ◽  
Acid Solutions ◽  
Ore Deposit ◽  
Natural Mineral ◽  
Sulfuric Acid Solutions ◽  
Natural Chalcopyrite

Anodic oxidation of the natural mineral chalcopyrite from the Bor ore deposit has been studied by cyclic voltammetry in pure sulfuric acid solutions. At the obtained voltammograms, the appearance of peaks at certain potential regions was identified and found to be much less pronounced than those previously reported in the literature. The voltammetric kinetic analysis confirmed that two-electron exchange electrochemical reactions occur. The explanation for this somewhat different electrochemical behavior of natural chalcopyrite compared to the concentrates widely used in studies of this mineral will also be given.

scholarly journals A mechanistic study of the EC′ mechanism – the split wave in cyclic voltammetry and square wave voltammetry

RSC Advances ◽  
2016 ◽  
Vol 6 (74) ◽  
pp. 70237-70242 ◽  
Author(s):  
Peng Song ◽  
Adrian C. Fisher ◽  
Jay D. Wadhawan ◽  
Joshua J. Cooper ◽  
Haydn J. Ward ◽  
...  
Keyword(s):  
Cyclic Voltammetry ◽  
Square Wave Voltammetry ◽  
Mechanistic Study ◽  
Electrochemical Reactions ◽  
Square Wave ◽  
Wave Voltammetry ◽  
Ec Mechanism

In this paper, a detailed investigation of electrochemical reactions coupled with homogenous chemical steps using cyclic voltammetry (CV) and square wave voltammetry (SWV) was carried out to study the electrocatalytic (EC′) mechanism.

Numerical Modeling of Cyclic Voltametry

2021 ◽  
Vol 105 (1) ◽  
pp. 561-566
Author(s):  
Petr Vyroubal ◽  
Martin Mačák
Keyword(s):  
Heat Transfer ◽  
Numerical Modeling ◽  
Cyclic Voltammetry ◽  
Temperature Fields ◽  
Electrochemical Reactions ◽  
New Approach ◽  
Cyclic Voltametry ◽  
Flow And Heat Transfer ◽  
Charging And Discharging Processes

This paper deals with a new approach to numerical modeling of cyclic voltammetry using the CFD solver FLUENT. The standard use of this solver is in the field of flow and heat transfer calculations, however, it is possible to model electrochemical reactions and it also includes basic models for calculations related to batteries, such as charging and discharging processes, temperature fields, etc. Thanks to the possibility of scripting, however, it is possible to extend these tasks to a much more complex level.

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