Both-faces hindered porphyrins. Part 4. Synthesis of functionalized basket-handle porphyrins designed for a strict intramolecular axial ligation in superstructured complexes

1988 ◽  
pp. 283 ◽  
Author(s):  
Michel Momenteau ◽  
Bernard Loock ◽  
Christiane Huel ◽  
Jean-Marc Lhoste
Keyword(s):  
Axial Ligation

scholarly journals Axial Ligation and Stoichiometry of Heme Centers in Adrenal Cytochromeb561†

Biochemistry ◽  
2007 ◽  
Vol 46 (29) ◽  
pp. 8647-8658 ◽  
Author(s):  
Yury Kamensky ◽  
Wen Liu ◽  
Ah-Lim Tsai ◽  
Richard J. Kulmacz ◽  
Graham Palmer
Keyword(s):  
Axial Ligation

Characterization of the porous nature of a phthalocyanine derivative with axial ligation designed to prevent aggregation

2010 ◽  
Vol 14 (05) ◽  
pp. 389-396
Author(s):  
Carl A. Barker ◽  
Alan Massey ◽  
Aidan Rhodes ◽  
Martin R. Bryce ◽  
Ritu Kataky
Keyword(s):  
Force Microscopy ◽  
Selective Transport ◽  
Electrode Surfaces ◽  
Axial Ligation ◽  
Nanoporous Films ◽  
Atom Force Microscopy ◽  
Solvent Cast ◽  
Complementary Techniques

Judiciously designed phthalocyanines (Pcs), such as silicon-Pc bis(3,5-diphenyl)benzoate (1c), with axial substituents which prevent aggregation, can self-assemble to form ordered nanoporous films on electrode surfaces. In this paper, complementary techniques such as Scanning Kelvin Nanoprobe (SKN) microscopy, Atom Force Microscopy (AFM) and electrochemical measurements are used to demonstrate that films formed by silicon-Pc bis(3,5-diphenyl)benzoate allow size- and charge- selective transport of probe molecules through well-defined intermolecular cavities. In contrast, the analogs silicon-Pc bis(4-tert-butylbenzoate) (1a) and silicon-Pc bis(3-thienyl)acetate (1b) have different film morphologies when solvent-cast in the same manner and block the electrode surface. The role of the different axial substituents in orienting the molecules on the substrate is discussed.

Influence of axial ligation on the spin state and exchange coupling in heterotrimetallic bis[iron(III) porphyrin]-copper (II) maleonitrile triple-decker complexes

1987 ◽  
Vol 26 (12) ◽  
pp. 1930-1933 ◽  
Author(s):  
William E. Hatfield ◽  
C. Michael Elliot ◽  
Juergen Ensling ◽  
Kozo Akabori
Keyword(s):  
Spin State ◽  
Exchange Coupling ◽  
Axial Ligation

scholarly journals Axial ligation of the high-potential heme center in an Arabidopsis cytochrome b 561

FEBS Letters ◽  
2011 ◽  
Vol 585 (3) ◽  
pp. 545-548 ◽  
Author(s):  
Filip Desmet ◽  
Alajos Bérczi ◽  
László Zimányi ◽  
Han Asard ◽  
Sabine Van Doorslaer
Keyword(s):  
Cytochrome B ◽  
High Potential ◽  
Axial Ligation

Effects of axial ligation on the thermolysis of benzyl- and neopentylcobamides: analysis of the base-on effect

1991 ◽  
Vol 30 (18) ◽  
pp. 3420-3430 ◽  
Author(s):  
Kenneth L. Brown ◽  
Harold B. Brooks
Keyword(s):  
Axial Ligation

Photoinduced Axial Ligation and Deligation Dynamics of Nonplanar Nickel Dodecaarylporphyrins

2003 ◽  
Vol 125 (32) ◽  
pp. 9787-9800 ◽  
Author(s):  
Jennifer L. Retsek ◽  
Charles Michael Drain ◽  
Christine Kirmaier ◽  
Daniel J. Nurco ◽  
Craig J. Medforth ◽  
...  
Keyword(s):  
Axial Ligation
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