Clemmensen reduction. Part 8. Fragmentation reactions of 1,4-diketones

Author(s):  
John G. St. C. Buchanan ◽  
Douglas R. Crump ◽  
Brian R. Davis
1995 ◽  
Vol 48 (11) ◽  
pp. 1827 ◽  
Author(s):  
KE Bailey ◽  
BR Davis

Clemmensen reduction of a series of 3-acetylcycloalkanones yields, as the major product, an acyclic unsaturated ketone, the product of fragmentation. Some normal carbonyl-methylene reduction also occurs. A mechanistic rationale for the fragmentation is advanced.


1963 ◽  
Vol 13 (8) ◽  
pp. 346-347
Author(s):  
G. E. Risinger ◽  
J. A. Thompson
Keyword(s):  

2003 ◽  
Vol 18 (2-4) ◽  
pp. 203-208
Author(s):  
D.V. Fedorov ◽  
A.S. Jensen ◽  
E. Garrido

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