792. Adsorption from binary mixtures: determination of individual adsorption isotherms

1952 ◽  
pp. 4123 ◽  
Author(s):  
J. J. Kipling ◽  
D. A. Tester
Keyword(s):  
Binary Mixtures ◽  
Adsorption Isotherms ◽  
Individual Adsorption

scholarly journals Use of Microfluidic Capillary Electrophoresis for the Determination of Multi-Component Protein Adsorption Isotherms: Application to High-Throughput Analysis for Hydrophobic Interaction Chromatography

Pharmaceutics ◽  
2021 ◽  
Vol 13 (12) ◽  
pp. 2135
Author(s):  
Elena Lietta ◽  
Alessandro Pieri ◽  
Elisa Innocenti ◽  
Roberto Pisano ◽  
Marco Vanni ◽  
...  
Keyword(s):  
Capillary Electrophoresis ◽  
Binary Mixtures ◽  
High Throughput ◽  
Adsorption Isotherms ◽  
High Throughput Screening ◽  
Hydrophobic Interaction Chromatography ◽  
High Throughput Analysis ◽  
High Throughput Experiments ◽  
Component Adsorption

Chromatography is a widely used separation process for purification of biopharmaceuticals that is able to obtain high purities and concentrations. The phenomena that occur during separation, mass transfer and adsorption are quite complex. To better understand these phenomena and their mechanisms, multi-component adsorption isotherms must be investigated. High-throughput methodologies are a very powerful tool to determine adsorption isotherms and they waste very small amounts of sample and chemicals, but the quantification of component concentrations is a real bottleneck in multi-component isotherm determination. The behavior of bovine serum albumin, Corynebacterium diphtheriae CRM197 protein and lysozyme, selected as model proteins in binary mixtures with hydrophobic resin, is investigated here. In this work we propose a new method for determining multi-component adsorption isotherms using high-throughput experiments with filter plates, by exploiting microfluidic capillary electrophoresis. The precision and accuracy of the microfluidic capillary electrophoresis platform were evaluated in order to assess the procedure; they were both found to be high and the procedure is thus reliable in determining adsorption isotherms for binary mixtures. Multi-component adsorption isotherms were determined with a totally high-throughput procedure that turned out to be a very fast and powerful tool. The same procedure can be applied to every kind of high-throughput screening.

Determination of the degree of adsorption and the heat of adsorption for 1-butylamine and ammonia on NaHY zeolites

1984 ◽  
Vol 49 (12) ◽  
pp. 2739-2743 ◽  
Author(s):  
Miloslav Křivánek ◽  
Pavel Jírů
Keyword(s):  
Lewis Acid ◽  
Adsorption Isotherms ◽  
Heat Of Adsorption ◽  
Brønsted And Lewis Acid

The degree and heat of adsorption of 1-butylamine and ammonia were measured on samples of NaHY zeolites activated at 400-600°C. The adsorption isotherms and calorimetric curves were compared for the two bases, and the amount of Bronsted and Lewis acid centres was determined from the calorimetric curves.

scholarly journals Significance of the particle physical properties and the Geldart group in the use of correlations for the prediction of minimum fluidization velocity of biomass–sand binary mixtures

2021 ◽  
Author(s):  
Louis Edwards Cáceres-Martínez ◽  
Diana Carolina Guío-Pérez ◽  
Sonia Lucía Rincón-Prat
Keyword(s):  
Physical Properties ◽  
Binary Mixtures ◽  
Minimum Fluidization Velocity ◽  
Fluidization Velocity ◽  
Minimum Fluidization ◽  
Mass Fractions ◽  
Char Particle ◽  
Geldart Groups ◽  
Biomass Particles

AbstractThe present study explores the relevance of the physical properties of biomass particles on the determination of the minimum fluidization velocity (Umf) of binary mixtures. Fluidization experiments were performed in a cold flow unit with diverse biomasses mixed with sand in different mass fractions. Gas velocity and pressure drop across the bed were used to determine Umf. Different correlations reported in the literature were evaluated on their ability to accurately predict Umf of the mixtures. Results showed satisfactory predictions when appropriately identifying correlations according to the corresponding Geldart groups for the biomass particles. This perspective opens new possibilities toward the generalization of correlation factors and helps in improving the accuracy of the prediction for highly heterogeneous mixtures. The methodology also allows the analysis of mixtures for which the experimental approach is difficult, such as those including char particle, with the only requirement of carefully measuring the physical properties of the particles.

scholarly journals Comparison of different models to calculate the viscosity of biogas and biomethane in order to accurately measure flow rates for conformity assessment

2021 ◽  
Vol 11 (1) ◽  
Author(s):  
Karine Arrhenius ◽  
Oliver Büker
Keyword(s):  
Binary Mixtures ◽  
Flow Rate ◽  
Correction Method ◽  
Gas Mixtures ◽  
Conformity Assessment ◽  
Flow Rates ◽  
Unknown Composition

AbstractThe study presents an optimised method to correct flow rates measured with a LFE flowmeter pre-set on methane while used for gas mixtures of unknown composition at the time of the measurement. The method requires the correction of the flow rate using a factor based on the viscosity of the gas mixtures once the composition is accurately known. The method has several different possible applications inclusive for the sampling of biogas and biomethane onto sorbent tubes for conformity assessment for the determination of siloxanes, terpenes and VOC in general. Five models for the calculation of the viscosity of the gas mixtures were compared and the models were used for ten binary mixtures and four multi-component mixtures. The results of the evaluation of the different models showed that the correction method using the viscosity of the mixtures calculated with the model of Reichenberg and Carr showed the smallest biases for binary mixtures. For multi-component mixtures, the best results were obtained when using the models of Lucas and Carr.

LINURON ADSORPTION AND THE DEGREE OF DECOMPOSITION OF PEATS AS MEASURED BY RUBBED FIBRE CONTENT AND PYROPHOSPHATE INDEX

1976 ◽  
Vol 56 (2) ◽  
pp. 105-109 ◽  
Author(s):  
H. MORITA
Keyword(s):  
Adsorption Isotherms ◽  
Fibre Content ◽  
Extraction Technique ◽  
Adsorption Coefficient ◽  
Column Extraction

Determination of the Freundlich adsorption isotherms for linuron with some peats showed that the adsorption coefficient, K, is closely related to the degree of decomposition as measured by the rubbed fibre content and the pyrophosphate index. The K values indicate that adsorption increases with decomposition. The analyses required for the determination of K were facilitated by the use of a column extraction technique.

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