Effect of preparation method on the surface acidity and catalytic performance of iron orthophosphates in cyclohexene conversion

1995 ◽  
Vol 5 (11) ◽  
pp. 2019 ◽  
Author(s):  
Juan M. Campelo ◽  
Maria S. Climent ◽  
Jose M. Marinas ◽  
Antonio A. Romero ◽  
Jos� A. Navio ◽  
...  
2013 ◽  
Vol 38 (31) ◽  
pp. 13649-13654 ◽  
Author(s):  
Dae-Woon Jeong ◽  
Won-Jun Jang ◽  
Jae-Oh Shim ◽  
Hyun-Seog Roh ◽  
In Hyuk Son ◽  
...  

RSC Advances ◽  
2017 ◽  
Vol 7 (77) ◽  
pp. 48662-48669 ◽  
Author(s):  
Jindou Hou ◽  
Wen. Luo ◽  
Shizhong Luo ◽  
Chao Lin ◽  
Ping Liu ◽  
...  

Synthesis of 2-methylpyrazine requires the well-designed CuMAl catalysts with bifunctional sites. Through alternating M species (M = Cr, Mn, Zn, and Co), highly dispersed Cu0 and high surface acidity can be achieved, thereby approaching the optimized catalytic performance.


2015 ◽  
Vol 15 (10) ◽  
pp. 8311-8317 ◽  
Author(s):  
Joongwon Lee ◽  
Seungwon Park ◽  
Ung Gi Hong ◽  
Jin Oh Jun ◽  
In Kyu Song

Surface modification of phosphorous-containing porous ZSM-5 catalyst (P/C-ZSM5-Sil.(X)) was carried out by a chemical liquid deposition (CLD) method using tetraethyl orthosilicate (TEOS) as a silylation agent. Different amount of TEOS (X = 5, 10, 20, and 30 wt%) was introduced into P/C-ZSM5il.(X) catalysts for surface modification. The catalysts were used for the production of light olefins (ethylene and propylene) through catalytic cracking of C5 raffinate. It was found that external surface acidity of P/C-ZSM5-Sil.(X) catalysts significantly decreased with increasing TEOS content. In the catalytic reaction, both conversion of C5 raffinate and yield for light olefins showed volcano-shaped curves with respect to TEOS content. Among the catalysts tested, P/C-ZSM5- Sil.(20) catalyst exhibited the best catalytic performance in terms of conversion of C5 raffinate and yield for light olefins. Thus, an optimal TEOS content was required for CLD treatment to maximize light olefin production in the catalytic cracking of C5 raffinate over P/C-ZSM5-Sil.(X) catalysts.


2011 ◽  
Vol 396 (1-2) ◽  
pp. 8-13 ◽  
Author(s):  
Yuwang Han ◽  
Cuiyun Lu ◽  
Dongsheng Xu ◽  
Yelong Zhang ◽  
Yi Hu ◽  
...  

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