Organophosphorus compounds of sulphur and selenium. Part XXXV. Oxophosphoranesulphenamides. Reactions of dialkylaminosulphenyl chlorides with dialkyl and trialkyl phosphites

1966 ◽  
pp. 2249 ◽  
Author(s):  
J. Michalski ◽  
B. Pliszka-Krawiecka
Keyword(s):  
Organophosphorus Compounds ◽  
Trialkyl Phosphites

Organophosphorus Compounds, XXVI * The Reaction of Diazoketones with Trialkyl Phosphites

1977 ◽  
Vol 32 (11) ◽  
pp. 1287-1290 ◽  
Author(s):  
M. M. Sidky ◽  
F. M. Soliman ◽  
A. A. El Kateb
Keyword(s):  
Reaction Mechanisms ◽  
Organophosphorus Compounds ◽  
Diazo Compound ◽  
Trialkyl Phosphites

Diazoketones 1, 8, 10 and 14 react with trialkyl phosphites to give different products depending upon the structure of the diazo compound, the type of the solvent and the nature of the phosphite ester used. Possible reaction mechanisms are discussed and the structural assignements are based on analytical, chemical and spectroscopic results.

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