Electrophilic aromatic substitution. Part XI. The kinetics and mechanism of the nitration of reactive aromatic substrates in acetic anhydride

1971 ◽  
pp. 2461 ◽  
Author(s):  
S. R. Hartshorn ◽  
J. G. Hoggett ◽  
R. B. Moodie ◽  
K. Schofield ◽  
M. J. Thompson
Keyword(s):  
Acetic Anhydride ◽  
Kinetics And Mechanism ◽  
Electrophilic Aromatic Substitution ◽  
Aromatic Substitution ◽  
Aromatic Substrates

Mechanism of alkenylation of aromatic substrates with 5-nitro-2-furylvinyl bromide

1986 ◽  
Vol 51 (9) ◽  
pp. 2013-2018
Author(s):  
Ján Hrabovský ◽  
Jaroslav Kováč ◽  
František Považanec
Keyword(s):  
Electrophilic Addition ◽  
Point Of View ◽  
Electrophilic Aromatic Substitution ◽  
Aromatic Substitution ◽  
H Nmr ◽  
Aromatic Substrates ◽  
Nmr Study ◽  
Elimination Pathway

Mechanism has been studied of electrophilic aromatic substitution with (Z)- and (E)-5-nitro-2-furylvinyl bromide in the presence of aluminium(III) chloride. From chemical findings and 1H NMR study it follows that the mechanism can be interpreted as an electrophilic addition-elimination pathway (AdE-E) from the point of view of the vinyl substitution.

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