The influence of the nitro-group upon side-chain reactivity. Part VII. Substitution and elimination reactions in 2-chloropropene systems

1970 ◽  
pp. 412 ◽  
Author(s):  
Y. Iskander ◽  
A. M. G. Nassar ◽  
R. Tewfik
Keyword(s):  
Nitro Group ◽  
Side Chain ◽  
Elimination Reactions

THE IONIZATION CONSTANTS OF p-NITROPHENYLACETIC AND PHENYLMALONIC ACIDS

1933 ◽  
Vol 8 (5) ◽  
pp. 447-449 ◽  
Author(s):  
Steward Basterfield ◽  
James W. Tomecko
Keyword(s):  
Benzoic Acid ◽  
Nitro Group ◽  
Malonic Acid ◽  
Phenylacetic Acid ◽  
Ionization Constants ◽  
Side Chain ◽  
Cooh Group ◽  
Conductivity Data ◽  
Nitrobenzoic Acid ◽  
Phenylmalonic Acid

The ionization constants of p-nitrophenylacetic and phenylmalonic acids have been determined from conductivity data. The value of K for p-nitrophenylacetic acid at 25 °C. is 1.04 × 10−4, about twice that of phenylacetic acid. The nitro group in the nucleus has not as powerful an effect on the ionization when the COOH group is in the side chain as it has when both nitro group and COOH are in the nucleus. K for p-nitrobenzoic acid is six times as great as K for benzoic acid. K for phenylmalonic acid is 2. 77 × 10−3 as compared with 1.6 × 10−3 for malonic acid.

scholarly journals Crystal structure of 2-phenylethylaminium 4-nitrophenolate monohydrate

2014 ◽  
Vol 70 (12) ◽  
pp. o1280-o1280
Author(s):  
N. Swarna Sowmya ◽  
S. Sampathkrishnan ◽  
S. Sudhahar ◽  
R. Mohan Kumar ◽  
G. Chakkaravarthi
Keyword(s):  
Crystal Structure ◽  
Hydrogen Bonds ◽  
Nitro Group ◽  
Aromatic Ring ◽  
Three Dimensional ◽  
Side Chain ◽  
Stacking Interactions ◽  
Dimensional Network ◽  
Centroid Distance ◽  
Molecular Salt

In the title hydrated molecular salt, C8H12N+·C6H4NO3−·H2O, the conformation of the side chain in the cation isanti[C—C—C—N = 179.62 (12)°] and the dihedral angle between the aromatic ring and the nitro group in the anion is 3.34 (11)°. In the crystal, the components are linked by O—H...O and N—H...O hydrogen bonds, generating (10-1) sheets, which featureR44(21) loops. The sheets interact by weak aromatic π–π stacking interactions [centroid–centroid distance = 3.896 (3) Å], forming a three-dimensional network.

ChemInform Abstract: SYNTHESIS OF BENZIMIDAZOLES WITH A NITRO GROUP IN THE SIDE CHAIN

1976 ◽  
Vol 7 (9) ◽  
pp. no-no
Author(s):  
V. V. RUDCHENKO ◽  
V. A. BUEVICH ◽  
V. S. GRINEVA ◽  
V. V. PEREKALIN
Keyword(s):  
Nitro Group ◽  
Side Chain
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