Crystal structure and Mössbauer spectrum of dimethyltin dichloride

1970 ◽  
Vol 0 (0) ◽  
pp. 2862-2866 ◽  
Author(s):  
Alwyn G. Davies ◽  
H. Judith Milledge ◽  
David C. Puxley ◽  
Peter J. Smith
1986 ◽  
Vol 41 (10) ◽  
pp. 1191-1195 ◽  
Author(s):  
Ute Patt-Siebel ◽  
Somluck Ruangsuttinarupap ◽  
Ulrich Müller ◽  
Jürgen Pebler ◽  
Kurt Dehnicke

S5N5[SnCl5(CH3CN)] is prepared by the reaction of SnCl2 with trithiazyl chloride in acetonitrile suspension. The compound is characterized by its IR spectrum, the 119Sn Mössbauer spectrum and by an X-ray crystal structure determination (1851 observed, independent reflexions, R = 0.024). S5N5[SnCl5(CH3CN)] crystallizes in the monoclinic space group P21/n with Z = 4 and the lattice dimensions a = 758.8; b = 1574.6; c = 1429.1 pm; β = 97.65°. The compound consists of planar S5N5® cations with the azulene-like structure, and anions [SnCl5(CH3CN)]e in which the tin atom has a distorted octahedral coordination. The bond angle Sn-N ≡ C (168°) is surprisingly small.


1989 ◽  
Vol 159 (3) ◽  
pp. 188-194 ◽  
Author(s):  
S.T. Lin ◽  
C.L. Lin ◽  
K.C. Lin ◽  
C. Tien ◽  
I.M. Jiang

1976 ◽  
Vol 37 (C6) ◽  
pp. C6-653-C6-655
Author(s):  
G. LANGOUCHE ◽  
B. B. TRIPLETT ◽  
N. S. DIXON ◽  
S. S. HANNA ◽  
P. BOOLCHAND

1974 ◽  
Vol 35 (C6) ◽  
pp. C6-309-C6-313
Author(s):  
M. KATO ◽  
Y. ISHIDA ◽  
K. SASSA ◽  
S. UMEYAMA ◽  
M. MORI

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